Loading...
sr-102610-3bCity Council Meeting: October 26, 2010 Agenda Item: ~'~ To: Mayor and City Council From: Susan Cline, Acting Director of Public Works Subject: Report on Water Quality and Public Health Goals Recommended Action Staff recommends that the City Council: 1. Concur that the following two recommended actions related to the City's 2010 report on water quality are exempt from review pursuant to the California Environmental Quality Act (CEQA) Guidelines Section 15061 (b). 2. Conduct a public hearing for the purpose of accepting and receiving public comments on the attached City of Santa Monica Report on Water Quality Relative to Public Health Goals (Attachment A). 3. Accept the attached report. Executive Summary Provisions of the California Health and Safety Code Section 116470 require public water systems serving more than 10,000 customers to prepare a report every three years that includes information on the detection of any elements in the water at levels above Public Health Goals (PHGs) or the equivalent Maximum Contaminant Level Goals (MCLGs). PHGs are adopted by the State Office of Environmental Health Hazard Assessment. and MCLGs are set by the United States Environmental Protection Agency (EPA). A public hearing is required to accept and receive public comments on the report. Staff has prepared the attached report (Attachment A) to provide information on the quality of its drinking water supply relative to adopted PHGs and MCLGs. Discussion The California Department of Public Health and the EPA are responsible for setting regulations and drinking water standards and goals. Drinking water goals include PHGs and MCLGs. PHGs are set by the State Office of Environmental Health Hazard Assessment and they are the recommended target levels. MCLGs are set by EPA and 1 are the levels of contaminants in drinking water below which there is no known or expected risk to public health. Both PHGs and MCLGs are not water quality standards and they are not required to be met by any public water system. PHGs and MCLGs are goals identifying extremely small risks. These are risks when, normally assessed, one person in one million would be at risk to a contaminant based on assessments made using assumptions and theoretical extrapolations. Drinking water standards are referenced as Maximum Contaminant Levels (MCLs) and Notification Levels (NLs). MCLs are the highest level of a contaminant allowed in drinking water. They are set as closely to PHGs and MCLGs as economically and technically feasible. MCLs are enforceable water quality standards that public water systems must meet. NLs are the concentrations of a contaminant which, if exceeded, triggers treatment or other requirements that public water system must follow. The City's drinking water supply complies with all Federal and State drinking water standards. The attached report (Attachment A) has been prepared pursuant to the requirements of the State Health and Safety Code. The report compares the quality of the City's groundwater and imported supplies with PHGs and MCLGs. The water quality of the City's water system complies with all of the health-based drinking water standards established by the California Department of Public Health and EPA. Substances in the City's water supply are below the applicable MCLs required by these regulatory agencies. Copies of the report are available for public review at the City Clerk's office, the Water Resources Division office, the Main Library, and online at the Water Resources' homepage. Environmental Analysis The City of Santa Monica Report on Water Quality Relative to Public Health Goals is categorically exempt from the California Environmental Quality Act (CEQA) as a Class 8 2 exemption (Section 15308 of the CEQA Guidelines), actions by regulatory agencies for the protection of the environment. Financial Impacts & Budget Actions There is no budget/financial impact associated with the recommended actions. Prepared by: Gil Borboa, P.E., Water Resources Manager Approved: Acting Director of Public Works Forwarded to Council: --`°°, ~._ -~~ `ay b Rod Gould City Manager Attachments: A -City of Santa Monica Report on Water Quality and Public Health Goals, June 2010 B -Summary of City of Santa Monica Report on Water Quality and Public Health Goals 3 ATTACHMENT A CITY OF SANTA MONICA REPORT ON WATER QUALITY RELATIVE TO PUBLIC HEALTH GOALS June 2010 The California legislatute has established the concept of a Public Health Goal (PHG). PHGs are established by the California Environmental Protection Agency (CaUEPA) Office of Environmental Health Hazard Assessment (OEHHA). A PHG is a health risk assessment, not a proposed drinking water standard. It is the level of a contaminant in drinking water, which is considered not to pose a significant risk to health if consumed for a lifetime. This determination is made without regard to cost or treatability. The California Department of Public Health (CDPH) uses PHGs in the evaluation of health- related drinking water standards, known as Maximum Contaminant Levels (MCLs). CDPH uses PHGs to identify MCLs that are to be reviewed for possible revision or when setting new MCLs for unregulated chemicals. Provisions of the California Health arid Safety Code Section 116470(b) (Exhibit A) requires that large water utilities (>10,000 service connections) prepare a special report by July 1, 2010 if their waterquality measurements have exceeded any PHGs in the three previous calendar years. The law also requires that where OEHHA has not adopted a PHG for a contaminant, the water suppliers are to use the Maximum Contaminant Level Goal (MCLG) adopted by the United States Environmental Protection Agency (USEPA). MCLGs are the federal equivalent to PHGs, but are not identical. Only constituents which have a California primary drinking water standard and for which either a PHG or MCLG has been set are to be addressed in this report. Exhibit B is a list of all regulated constituents with MCLs and PHGs or MCLGs. There are a few constituents that are routinely detected in water systems at levels usually well below the drinking water standards for which no PHG nor MCLG has yet been adopted by OEHHA or USEPA. These include total trihalomethanes (TTHMs) among others. Water Resources Division June 2010 Page 1 This report provides the following information as specified in the Health and Safety Code (Exhibit A) for each constituent detected in the City of Santa Monica's (City) water supply in 2007, 2008, and 2009 at a level exceeding an applicable PHG or MCLG: • Numerical public health risk associated with the MCL and the PHG or MCLG (Exhibit C). • Category or type of risk to health that could be associated with each constituent. • Best Available Treatment Technology that could be used to reduce the constituent level. • Estimate of the cost to install that treatment if it is appropriate and feasible. WHAT ARE PHGs? PHGs are set by the California Office of Environmental Health Hazard Assessment (OEHHA) which is part of Cal/EPA. PHGs are based solely on public health risk considerations. None of the risk- managementfactors that are considered by CDPH in setting drinking water standards are considered in setting the PHGs. These factors include analytical detection capabilities, treatment technology available, benefits and costs. PHGs are not enforceable and are not required to be met by any public water system. MCLGs are federal equivalent to PHGs and are set by the USEPA. WATER QUALITY DATA CONSIDERED All of the water quality data collected for Santa Monica's water system between 2007 and 2009 for purposes of determining compliance with drinking water standards were considered. This information was summarized in tables included in the 2007, 2008 and 2009 Annual Water Quality Reports, which were mailed to all Santa Monica customers, residents, and businesses in June 2008, May 2009, and May 2010 (Exhibit D). Most of the constituents tested in the water were reported as Not Detected (ND) and are not generally listed in the Annual Water Quality Reports. When a constituent is reported as ND, it generally means that the laboratory did not detect the compound, but it could also mean that it was detected at a level less than California's Detection Level for purposes of Reporting (DLR). GUIDELINES FOLLOWED The Association of California Water Agencies (ACWA) formed a workgroup, which prepared guidelines for water utilities to use in preparing the PHG reports. These guidelines were used in the preparation of this report. No general guidelines are available from the state regulatory agencies. ACWA's workgroup also prepared guidelines for water utilities to use in estimating the costs to reduce a constituent to the Water Resources Division June 2010 Page 2 MCL. Exhibit E provides cost estimates for the best treatment technologies that are available today. BEST AVAILABLE TREATMENT TECHNOLOGY AND COST ESTIMATES Both the USEPA and CDPH have adopted what are known as Best Available Technologies (BATs), which are the best known methods of reducing contaminant levels. Capital construction and operation and maintenance (O&M) costs can be estimated for such technologies. However, since many PHGs and MCLGs are set much lower than the MCL, it is not always possible or feasible to determine what treatment is needed to further reduce a constituent down to or near the PHG or MCLG. For example, USEPA sets the MCLG for potential cancer-causing chemicals at zero. Estimating the costs to reduce a constituent to zero is difficult, if not impossible, because it is not possible to verify by analytical means that the level has been lowered to zero. In some cases, installing treatment to try and further reduce very low levels of one constituent may have adverse effects on other aspects of water quality. CONSTITUENTS DETECTED THAT EXCEED A PHG OR A MCLG The following is a discussion of constituents that were detected in one or more of the City's drinking water sources at levels exceeding the PHG, or if no PHG exists, above the MCLG. Santa Monica consistently delivers safe water at the lowest possible cost to its customers using multiple treatment methods approved by CDPH. Coristituents that were detected in one or more drinking water sources at levels above the MCLs are reduced to acceptable levels. The health risk information for regulated constituents with MCLs, PHGs or MCLGs is provided in Exhibit C. • Total Coliform Bacteria Total coliform bacteria are measured at approximately 100 sites around the City. No more than 5% of all samples collected in a month can be positive for total coliforms. This defines the MCL. Although there is no PHG for total coliform bacteria, the MCLG is zero positive samples. The reason for the total coliform drinking water standard is to minimize the possibility of the water containing pathogens, which are organisms that cause waterborne disease. Because total coliform analysis is only a surrogate indicator of the potential presence of pathogens, it is not possible to state a specific numerical health risk. While USEPA normally sets MCLGs "at a level where no known or anticipated adverse effects on persons would occur", EPA indicates that it cannot do so with total coliforms. Nevertheless, without the ability to determine a specific numerical risk, the MCLG has been set at zero for total coliform bacteria. Coliform bacteria are a group of indicator organisms that are ubiquitous in nature and are not generally considered harmful. They are used because of the ease in Water Resources Division June 2010 Page 3 monitoring and analysis. If a positive sample is found, it indicates a potential problem that needs to be investigated with follow-up sampling. It is not at all unusual for a system to have an occasional positive sample. In Santa Monica, about 80 of the sites where samples are taken for total coliform bacteria are taps, typically hose bibbs, on private residences or businesses. Many of these taps are exposed to the environment and while they provide a satisfactory sample point most of the time, occasionally the tap itself may become exposed to bacteria from the environment, e.g. overgrown plants, pets and humans. When samples are drawn from these exposed taps, they test positive on rare occasion. During 2007-2009, the City collected between 119 and 145 samples each month for total coliform analysis. On one occasion a sample was found to be positive for coliform bacteria. The water supply to the sample location did not appear compromised in any way (normal chlorine residual, appearance and odor) and follow-up samples were taken and tested negative. Additionally, the water leaving the treatment plant is tested on a weekly basis and always tested negative for coliform bacteria. The single positive sample occurred in June 2008 for a monthly total of 0.7% positive samples, well below the MCL of 5%. No samples were found to be positive for total coliform bacteria in 2007 or 2009. In an effort to reduce these occasional positive results, the Water Resources Division (Division) has a program to prioritize the sites and install more dedicated sampling stations. The dedicated samplers are enclosed in a lockable box and are protected from the environment. A total of four new boxes were installed during the period covered by this report with plans to complete several more this year in conjunction with the Division's main line replacement program. The Division already maintains an effective cross connection control program, a disinfectant residual throughout the system, an effective monitoring and surveillance program, and positive pressure in all parts of the distribution system. The Division has already taken all of the steps described by the California Department of Health. Services as Best Available Technology (BAT) for coliform Bacteria in Section 6447, Title 22, CCR. Since it is unlikely that any change to the treatment process at the Arcadia Water Treatment Plant would prevent the occasional positive test result at the distribution sampling sites, staff recommends no change to the existing treatment. • Trichloroethylene (TCE) The PHG for trichloroethylene (TCE) was increased to 0.0017 milligrams per liter (mg/I) in 2009. The MCL for TCE is 0.005 mg/I. The level of TCE in the City's groundwater and supplemental supplies was below the MCL at all times during the period of this report. Trichloroethylene is a volatile organic compound (VOC). It is a manmade solvent used since the 40's and 50's as a degreaser, parts cleaner, and in other industries. Water Resources Division June 2010 Page 4 In the last several decades, TCE has shown up increasingly in groundwater supplies in Southern California and elsewhere. TCE was discovered at low levels in several of the City's wells located along or near Olympic Boulevard in -1980. Initially the TCE from the Olympic Wells was diluted in the mixture with other, uncontaminated wells. As the TCE levels increased over time, several wells had to be turned off until treatment to remove the TCE could be installed. In 1992, the Division completed an expansion and upgrade to the Arcadia Treatment Plant that included mechanical aeration to remove TCE in the combined well flow to a level below the MCL of 0.005 mg/I. The contaminated Olympic Wells were placed back in service and have been blended and treated with the other wells since. The level of TCE in the water produced by the Arcadia Treatment Plant ranged from ND to 0.0025 mg/I for the period covered in this report. However, TCE was only found to be greater than the PHG of 0.0017 mg/I for some readings taken in 2009. The annual average TCE produced at the treatment plant was 0.0005, 0.0004 and 0.0007 mgll for 2007, 2008 and 2009 respectively. The category of health risk associated with TCE, and the reason that a drinking water standard was adopted for it, is that people who drink water containing TCE above the MCL for many years could experience an increased risk of getting cancer. CDPH says that "Drinking water which meets this standard (the MCL) is associated with little to none of this risk and should be considered safe with .respect to TCE." This language is taken from the California Code of Regulations (CCR), Title 22, Section 64468.2. The numerical health risk of ingesting drinking water with TCE above the PHG is 1X10-6, or one additional theoretical cancer case in one million people drinking two liters of water a day for 70 years. The health risk of ingesting water with TCE above the MCL is six additional theoretical cancer cases in one million people. The Best Available Technology (BAT) for TCE to lower the concentration below the MCL is either adsorption using liquid phase Granular Activated Carbon (GAC) or Packed Tower Aeration (PTA). Since the level of TCE remaining in the water produced by the treatment plant is already well below the MCL, additional treatment with GAC would be necessary to reliably reduce the TCE level to zero. However, the City is currently completing construction of a new Reverse Osmosis (RO) softening plant in conjunction with the Charnock Well Field Restoration Project. Although RO is not considered BAT for reduction of TCE, City staff anticipates that additional removal will be accomplished with the new treatment and recommend that no additional treatment be considered until the new facilities go online and can be evaluated for TCE removal. • Lead and Copper There are no MCLs for lead or copper. Lead and copper are not present in our water sources, but can leach into drinking water through the resident's plumbing systems and faucets. Instead of MCLs, every three years a set of special samples is Water Resources Division June 2010 Page 5 collected and the results evaluated to determine whether the City's water system has achieved "optimized corrosion control". The samples collected are first-draw at the tap of thirty or more homes identified as high-risk (new plumbing installed with lead solder before it was banned}. To meet drinking water standards, the 90th percentile reading (meaning 90% of the samples were lower) of all samples collected by the City from these household taps cannot exceed an Action Level (AL) of 0.015 mg/I for lead and 1.3 mg/I for copper. The PHG for lead was lowered to 0.0002 mg/I in 2009 and copper was increased to 0.3 mg/I in 2008. The last round of testing for lead and copper was conducted by the Water Resources Division in 2007 (next round is summer 2010). The 90th percentile reading for lead in the last round was 0.0043 mg/I and was 0.24 mg/I for copper. These are below the Action Levels, which means the City continued to meet water quality standards for lead and copper and was again considered to have "optimized corrosion control". The value for copper was lower than the PHG, but the level for lead was higher than its corresponding PHG. There are two categories of health risk associated with lead -chronic toxicity (neurobehavioral effects in children, hypertension in adults) and cancer. The numerical health risk of ingesting drinking water with lead above the PHG is 2X10-6, or two additional theoretical cancer cases in one million people drinking two liters of water a day for 70 years. As stated previously, the City's water supply is considered to have "optimized corrosion control". In general, optimizing corrosion control is considered to be BAT to address corrosion issues and any lead and copper findings. The Division will continue to monitor water quality parameters that relate to corrosivity such as pH, hardness, alkalinity and total dissolved solids and will take action, if necessary to maintain our system in an "optimized corrosion control" condition. Since the City's water supply continues to meet the "optimized corrosion control" requirements, it is not prudent to initiate additional corrosion control treatment until such time as changirig conditions might warrant further action. Therefore, no estimate of cost has been included in this report and no recommendations for further action are advised. • Arsenic The PHG for arsenic is 0.000004 mg/I. The MCL forarsenic is 0.01 mg/I. Arsenic is a naturally occurring metallic element found in water generally at low levels throughout California and elsewhere due tb the erosion of mineral deposits. It can also enter water supplies from runoff from agricultural and industrial sites. The MCL was lowered in 2006 due to increasing evidence of potential detrimental health effects even at low levels. The concern is that long-term exposure to arsenic in drinking water may cause skin damage or problems with circulatory systems, and may cause cancer. Water Resources Division June 2010 Page 6 Arsenic was below the MCL in all of the City's water sources at all times during the period covered in this report, however all sources exceeded the PHG at least once during this period. Arsenic readings for all sources for the period covered by this report ranged from ND (Reporting Limit was 0.002 mg/I) to a high of 0.0039 mg/I in the water purchased from the Metropolitan Water District's (MWD) Jensen Treatment Plant. Annual averages for the Jensen supply and for the water from MWD's Weymouth Treatment Plant ranged from ND for both in 2007 to 0.0031 mg/I for the Jensen supply in 2009. Local groundwater supplies had annual averages for this period that ranged from 0.0007 mg/I for Santa Monica Well #1 in 2007 to 0.0017 mg/I for water coming from. the Arcadia Treatment Plant for both 2008 and 2009. The category of health risk associated with arsenic is that people who drink water containing arsenic above the MCL for many years could experience an increased cancer risk. The numerical health risk of ingesting drinking water with arsenic above the PHG is 1X10-6, or one additional theoretical cancer cases in one million people drinking two liters of water a day for 70 years. There are two BATS designated for arsenic removal, Ion Exchange and Reverse Osmosis (RO). As stated previously, the City is currently completing construction of a new RO softening plant in conjunction with the Charnock Well Field Restoration Project and it is anticipated that arsenic levels in the water coming from the Arcadia Treatment Plant will be lower in the future. However, BATS are designed for treatment to achieve compliance with the corresponding MCL only, and not PHGs. It is unlikely that arsenic will be removed to a level lower that the very low PHG for arsenic. In any case, that level is lower than laboratory tests can detect, so it would be impossible to confirm whether water coming from the Arcadia Treatment Plant, or any given water supply, actually has arsenic lower than the PHG level because it cannot be measured at that level. It is not practical or feasible to estimate costs for the reduction of arsenic from the supplemental water the City purchases from MWD, so no such determination will be attempted here and no recommendations for further action are advised. • Uranium The PHG for uranium is 0.43 picoCuries per liter (pCi/I) and the MCL is 20 pCi/I. Uranium is a naturally occurring metallic element which is weakly radioactive and is ubiquitous in the earth's crust. Uranium is found in ground and surface waters due to its natural occurrence in geological formations. The average uranium. concentrations in surface and ground water are 1 and 2 pCi/I respectively. The uranium intake from water is about equal to the total from other dietary components. Water Resources Division June 2010 Page 7 Uranium was below the MCL for all watersources at all times during the period covered in this report, however all sources exceeded the PHG at least once during this period. Uranium readings for the period covered by this report ranged from ND (Reporting Limit was 1 pCi/I) to a high of 4.5 pCi/I in the water coming from the Arcadia Treatment Plant. Annual averages for each of the supplies ranged from ND for the Weymouth supply in 2007 to 4.5 pCi/I for water coming from the Arcadia Treatment Plant in 2009 mg/I. The category for health risk associated with uranium is that people who drink water containing uranium above the MCL for many years could experience an increased cancer risk. OEHHA has determined that the numerical cancer risk for uranium above the PHG level is 1x10-6, or one additional theoretical cancer cases in one million people drinking two liters of water a day for 70 years. There are several BATS designated to lower uranium to below the MCL including RO. The new RO softening plant due to come online later this year is anticipated to remove uranium levels from the City's groundwater supply. However, BATS are designed for treatmentto achieve compliance with the corresponding MCL only, and not PHGs, so evaluation of this water against the PHG will be determined only after start-up and will be addressed in future reports. ' The City's single well not treated by the Arcadia Treatment Plant is Santa Monica Well #1. The water for this well had a uranium level that ranged from 0.8 to 0.9 pCi/I for the period covered by this report and so must be evaluated for treatment for removal of uranium to below the PHG. Of the designated BATs for uranium, the most effective and economical approach would be to use RO treatment at the well site. Based on 2009 flow rates and estimated costs, this would be in the range of $334,000 per year not including the cost for waste (brine) disposal. However, this well is located in the center median of San Vicente Blvd in a residential neighborhood where it would not be feasible to construct even a small treatment plant at the well site. Again, it is also unclear whether treatment to below the PHG for uranium could be achieved using RO as BATs are designed to achieve compliance only to the corresponding MCL. It should also be noted that this cost estimate may be imprecise as treatment costs can vary widely depending on the particulars of the situation. It is not practical or feasible to estimate costs for the reduction of uranium from the supplemental water the City purchases from MWD, so no such determination will be attempted here and no recommendations for further action are advised. • Other Radionuclides There are several radionuclides for which OEHHA has not set PHGs, but for which an MCLG has been designated by USEPA. The standards are for radionuclides including: alpha emitters, beta/photon emitters, combined radium as well as the standard for uranium described above. In addition to these standards, USEPA has Water Resources Division June 2010 Page 8 designated an MCLG of zero for each. The groundwater and supplemental water supplies for Santa Monica met the MCLs for these constituents at all times during the period covered by this report, but the MCLGs of zero for some of these radionuclides were exceeded at some sources at various times during this period. Radionuclides are radioactive elements that are found in nature or are man-made. They are unstable and emit particles or waves of high energy from the nucleus or other parts of the atom. There are three basic kinds ofhigh-energy radiation: alpha, beta, and gamma (included in a broader group called photons). Many radionuclides emit more than one kind of radiation, but are classified by their most important kind. The MCL for alpha emitters limits the level of "gross alpha" radiation other than what is contributed by uranium and radon. The MCL for beta/photon emitters limits the level of radiation from a group of 179 man-made radioactive materials. The MCL for combined radium limits the radiation on two kinds (or "isotopes") of radium: radium- 226 and radium-228. These MCLs were adopted to address concern with the health effects from radiation inside the body after consuming the radionuclides as evidence suggests that long-term exposure to radionuclides in drinking water may cause cancer. The level of alpha emitters in the City's groundwater and supplemental supplies was below the MCL of 15 pCi/I at all times during the period covered by this report, but exceeded the MCLG of zero in some monitoring data. Gross alpha readings for the period covered by this report ranged from ND (Reporting Limit was 3 pCi/I) for all supplies at various times to a high of 7.6 pCi/I in the water coming from the Weymouth supply in 2008. Annual averages ranged from ND for some of the supplies to 5.2 pCi/I for water coming from MWD's Weymouth Treatment Plant in 2008. The standard for beta/photon emitters does not apply to the City's groundwater and as such, is not covered by this report. However, the supplemental water the City receives from MWD met the MCL of 50 pCill for beta/photon emitters at all times, but exceeded the MCLG of zero in some monitoring data. Readings for beta/photon emitters for both MWD supplies for the period covered by this report ranged from ND (Reporting Limit was 4 pCi/I) to a high 9.7 pCi/I in the water coming from MWD's Weymouth Treatment Plant in 2008. The annual averages ranged from ND for the Jensen supply to 4.2 pCi/I for the Weymouth supply in 2008. The level of combined radium in the City's groundwater and supplemental supplies was below the MCL of 5 pCi/1 at all times during the period covered by this report, but exceeded the MCLG of zero only once for one reading of 0.8 pCi/I (Reporting Limit was 0.6 pCi/I) in Santa Monica Well #1 in 2007. No other detection of combined radium was reported for the period covered by this report. The BATS for these radionuclides are the same as for uranium. The new RO softening plant due to come online later this year is anticipated to remove to some extent, these other radionuclides from the City's groundwater supply as well. As Water Resources Division June 2010 Page 9 explained previously, BATS are designed for treatment to achieve compliance with the corresponding MCL only, and not PHGs or MCLGs, so evaluation of this water against the MCLGs for these other radionuclides will be determined only after start- up and will be addressed in future reports. Likewise, the analysis for treatment of Santa Monica Well #1 and the MWD supplies is the same as for uranium and no recommendations for further action are advised. • Bromate The PHG for Bromate was set at 0.0001 mg/I in 2009. The MCL for Bromate is 0.010 mg/I. Bromate is a disinfection byproduct (DBP) formed when water containing naturally occurring bromide ion is ozonated. The MCL for Bromate does not apply to single readings but is instead compared to a Running Annual Average ~R~)• The MCL was adopted in 2002 to address concern with potential health effects as evidence suggests that long-term exposure to Bromate in drinking water may cause cancer. The standard applies only to water treatment plants that apply ozone for disinfection or other purposes, and so does not apply to the City's groundwater. However; the supplemental water the City receives from MWD's Jensen Treatment Plant is ozonated and met the RAA MCL for Bromate of 0.010 mg/I at all times, but exceeded the PHG for the period covered by this report. The Jensen Treatment Plant was retrofitted with ozone in 2005 as part of MWD's plan to implement ozonation at all six of their treatment plants. The purpose of the retrofit is to insure compliance with new requirements for disinfection of surface waters and new DBP regulations, as well as an improvement in the plants' ability to handle taste and odor episodes resulting from periodic algal blooms in MWD's source reservoirs. As expected, the switch to ozone at the Jensen Treatment Plant resulted in reductions of total trihalomethanes and haloacetic acids, which are classes of DBPs that are also regulated. However, Bromate itself is a DBP and the formation of which is a consequence of the switch in disinfectant. Bromide readings for the Jensen Treatment Plant for the period covered by this report ranged from 0.003 to 0.012 mg/I. The highest RAA was 0.0078 mg/I for2008 and demonstrated compliance with the MCL as did all other RAAs for 2007 and 2009. The category for health risk associated with Bromate is that people who drink water containing Bromate above the MCL for many years could experience an increased risk of getting cancer. OEHHA has determined that the numerical cancer risk for Bromate above the PHG level is 1x10-6, or one additional theoretical cancer cases in one million people drinking two liters of water a day for 70 years. The BAT to reduce Bromate is control of the ozone treatment process to reduce production of this DBP. As such, this is a process that is under the control and jurisdiction of MWD, is already being conducted and will not be addressed further in this report. Water Resources Division June 2010 Page 10 RECOMMENDATIONS FOR FURTHER ACTION The drinking water quality of the City of Santa Monica meets all State of California Department of Public Health and USEPA drinking water standards set to protect public health. To further reduce the levels of the constituents identified in this report that are already significantly below the established health-based Maximum Contaminant Levels (MCL) would typically require that additional costly treatment processes be constructed. The effectiveness of the treatment processes to provide any significant reductions in constituent levels at these already low values is uncertain. The health protection benefits of these further hypothetical reductions are not clear and may not be quantifiable. However, the City is currently completing construction of a new Reverse Osmosis (RO) softening plant in conjunction with the Charnock Well Field Restoration Project. Although RO was primarily chosen to provide amulti-barrier approach to MTBE removal, City staff anticipates that additional removal for many of the constituents addressed in this report will be accomplished with the new treatment and recommend that no additional treatment be considered until the new facilities go online and can be evaluated. Therefore, no action is proposed at this time. ADDITIONAL INFORMATION 1.4-Dioxane No MCL, MCLG, or PHG exists for 1,4-Dioxane, and as such, is not a requirement for this report. However, CDPH has set a Notification Level (NL) of 0.003 mg/I in drinking water for 1,4-Dioxane. As reported to City Council in 2002, the City's Olympic Wells (Santa Monica Wells 3&4) were found to have 1,4-Dioxane above the NL. The City was advised by CDPH in 2002 that it was acceptable to continue the use of these wells as long as the level remained less than 100 times the NL. EXHIBITS: A -California Health and Safety Code Section 116470(b) B -List of Regulated Constituents with MCLs, PHGs or MCLGs C -Numerical Health Risk Information D -Tables excerpted from Annual Water Quality Reports for 2007- 2009 E -Cost Estimates for Treatment Technologies F -Acronyms Water Resources Division June 2010 Page 11 EXHIBIT A Health & Safety Code Section 116470 (b) On or before July 1, 1998, and every three years thereafter, public water systems serving more than 10,000 service connections that detect one or more contaminants in drinking water that exceed the applicable public health goal, shall prepare a brief written report in plain language that does all of the following: (1) Identifies each contaminant detected in drinking water that exceeds the applicable public health goal. (2) Discloses the numerical public health risk, determined by the office, associated with the maximum contaminant level for each contaminant identified in paragraph (1) and the numerical public health risk determined by the office associated with the public health goal for that contaminant. (3) Identifies the category of risk to public health, including, but not limited to, carcinogenic, mutagenic, teratogenic, and acute toxicity, associated with exposure to the contaminant in drinking water, and includes a brief plainly worded description of these terms. (4) Describes the best available technology, if any is then available on a commercial basis, to remove the contaminant or reduce the concentration of the contaminant. The public water system may, solely at its own discretion, briefly describe actions that have been taken on its own, or by other entities, to prevent the introduction of the contaminant into drinking water supplies. (5) Estimates the aggregate cost and the cost per customer of utilizing the technology described in paragraph (4), if any, to reduce the concentration of that contaminant in drinking water to a level at or below the public health- goal. (6) Briefly describes what action, if any, the local water purveyor intends to take to reduce the concentration of the contaminant in public drinking water supplies and the basis for that decision. (c) Public water systems required to prepare a report pursuant to subdivision (b) shall hold a public hearing for the purpose of accepting and responding to public comment on the report. Public water systems may hold the public hearing as part of any regularly scheduled meeting. (d) The department shall not require a public water system to take any action to reduce or eliminate any exceedance of a public health goal. (e) Enforcement of this section does not require the department to amend a public water system's operating permit. (f) Pending adoption of a public health goal by the Office of Environmental Health Hazard Assessment pursuant to subdivision (c) of Section 116365, and in lieu thereof, public water systems shall use the national maximum contaminant level goal adopted by the United States Environmental Protection Agency for the corresponding contaminant for purposes of complying with the notice and hearing requirements of this section. (g) This section is intended to provide an alternative form for the federally required consumer confidence report as authorized by 42 U.S.C. Section 300g-3(c). EXHIBIT B MCLs, DLRs and PHGs for Regulated Drinking Water Contaminants Last Update: December 31, 2009 The following table includes: CDPH's maximum contaminant levels (MCLs) CDPH's detection limits for purposes of reporting (DLRs) Public health goals (PHGs) from the Office of Environmental Health Hazard Assessment (OEHHA) (Units are in milligrams per liter (mg/L), unless otherwise noted.) State MCL DLR PHG or MCLG Date of PHG Chemicals with MCLs in 22 CCR §64431-Inorganic Chemicals Aluminum 1 0.05 0.6 2001 Antimony 0.006 0.006 0.02a 1997 Arsenic 0.010 0.002 0.000004 2004 Asbestos (MFL =million fibers per liter; for fibers >10 microns Ion 7 MFL 0.2 MFL 7 MFL 2003 Barium 1 0.1 2 2003 Be Ilium 0.004 0.001 0.001 2003 Cadmium 0.005 0.001 0.00004 2006 Chromium, Total - OEHHA withdrew the 0.0025-m /L PHG 0.05 0.01 withdrawn Nov. 2001 1999 Chromium-6 -MCL to be established - currently regulated under the total chromium MCL -- 0.001 0.00006° C anide 0.15 0.1 0.15 1997 Fluoride 2 0.1 1 1997 Mercury (inorganic) 0.002 0.001 0.0012 1999 rev2005 Nickel 0.1 0.01 0.012 2001 Nitrate as NO3 45 2 45 1997 Nitrite as N 1 as N 0.4 1 as N 1997 Nitrate + Nitrite 10 as N -- 10 as N 1997 Perchlorate 0.006 0.004 0.006 2004 Selenium- 0.05 0.005 0.05 -- Thallium 0.002 0.001 0.0001 1999 rev2004 Copper and Lead, 22 CCR §64672.3 Values referred to as MCLs for lead and copper are not actually MCLs; instead, they are called 'Action Levels" under the lead and copper rule Co er t.3 4A5 d9.3 2008 :' Lead € 0'015 .0,005 t1.0042" ::2009..:; Radionuclides with MCLs in 22 CCR §64441 and §64443-Radioactivity [units are picocuries per liter (pCi/L), unless otherwise stated; n!a =not applicable] Gross alpha particle activity - OEHHA concluded in 2003 that a PHG was not ractical 15 3 (zero) n/a MCLs, DLRs and PHGs for Regulated Drinking Water Contaminants Last Update: December 31, 2009 State MCL DLR PHG or MCLG Date of PHG Gross beta particle activity - OEHHA concluded in 2003 that a PHG was not practical 4 mrem/yr 4 (zero) n/a Radium-226 -- 1 0.05 2006 Radium-228 -- 1 -0.019 2006 Radium-226 + Radium-228 (addressed to ether as one MCL 5 Strontium-90 8 2 0.35 2006 Tritium 20;000 1,000 400 2006 Uranium 20 1 0.43 2001 Chemicals with MCLs in 22 CCR §64444-Organic Chemicals (a) Volatile Organic Chemicals (VOCs) Benzene 0.001 0.0005 0.00015 2001 Carbon tetrachloride 0.0005 0.0005 0.0001 2000 1,2-Dichlorobenzene 0.6 0.0005 0.6 1997 (rev2009 1,4-Dichlorobenzene p-DCB 0.005 0.0005 0.006 1997 1,1-Dichloroethane 1,1-DCA 0.005 0.0005 0.003 2003 1,2-Dichloroethane (1,2-DCA) 0.0005 0.0005 0.0004 1999 rev2005 1,1-Dichloroeth lens 1,1-DCE 0.006 0.0005 0.01 1999 cis-1,2-Dichloroeth lens 0.006 0.0005 0.1 2006 trans-l,2-Dichloroeth lens 0.01 0.0005 0.06 2006 Dichloromethane (Methylene chloride) 0.005 0.0005 0.004 2000 1,2-Dichloro ro ane 0.005 0.0005 0.0005 1999 1,3-Dichloropropene 0.0005 0.0005 0.0002 1999 rev2006 Eth (benzene 0.3 0.0005 0.3 1997 Meth I tertia bu I ether MTBE 0.013 0.003 0.013 1999 Monochlorobenzene 0.07 0.0005 0.2 2003 Styrene 0.1 0.0005 0.1 ° 1,1,2,2-Tetrachloroethane 0.001 0.0005 0.0001 2003 Tetrachloroeth lens PCE 0.005 0.0005 0.00006 2001 Toluene 0.15 0.0005 0.15 1999 1,2,4-Trichoorobenzene 0.005 0.0005 0.005 1999 1,1,1-Trichloroethane 1,1,1-TCA 0.2 0.0005 1 2006 1,1,2-Trichloroethane 1,1,2-TCA Trichlokoefh lens'; CE 0:005 0:005 ~ 0.0005 "fl0005 0.0003 OA017 2006 :2009 Trichlorofluoromethane Freon 11 0.15 0.005 0.7 1997 1,1,2-Trichloro-1,2,2-Trifluoroethane (Freon 113 1 2 0.01 4 1997 Vin I chloride 0.0005 0.0005 0.00005 2000 X lenes 1.75 0.0005 1.8 1997 (b) Non-Volatile Synthetic Organic Chemicals (SOCs) Alachlor 0.002 0.001 0.004 1997 Atrazine 0.001 0.0005 0.00015 1999 MCLs, DLRs and PHGs for Regulated Drinking Water Contaminants Last Update: December 31, 2009 State MCL DLR PHG or MCLG Date of PHG Bentazon 0.018 0.002 0.2 1999 rev2009 Benzo(a)pyrene 0.0002 0.0001 0.000004° 1997 Carbofuran 0.018 0.005 0.0017 2000 Chlordane 0.0001 0.0001 0.00003 1997 rev2006 Dalapon 0.2 0.01 .0.79 1997 rev2009 1,2-Dibromo-3-chloropropane (DBCP) 2,4-DfGhlorophenoxyaceUc acid(2,4-Dj: 0.0002 0.07 0.00001 0.01 1.7E-06 "0.02 1999 '2009 , Di 2-eth Ihex I adipate 0.4 0.005 0.2 2003 Di 2-eth the I phthalate DEHP 0.004 0.003 0.012 1997 Dinoseb 0.007 0.002 0.014 1997 Di uat 0.02 0.004 0.015 2000 Endrin 0.002 0.0001 0.0018 1999 rev2008 Endothal 0.1 0.045 0.58 1997 Eth lene dibromide EDB GI phosate 0.00005 0.7 0.00002 0.025 0.00001 '0.9 2003 2007 Heptachlor 0.00001 0.00001 0.000008 1999 He tachlor a oxide 0.00001 0.00001 0.000006 1999 Hexachlorobenzene 0.001 0.0005 0.00003 2003 Hexachloroc clopentadiene 0.05 0.001 0.05 1999 Lindane 0.0002 0.0002 0.000032 1999 rev2005 Methox chlor 0.03 0.01 0.03 1999 Motinat~ Oxam '.I' ' 6.02 Q.D5 ' 6.002 0.02 D.OD1 6A26 12008 ' :2009 Pentachtoropheno] PCP OiD01 OA002 6.0003 ='2009 ~: Picloram 0.5 0.001 0.5 1997 Pol ehti~rinatedbi'hen Is PGBs - 0-0DD5 0:0005 0=00009 ;2007 Simazine 0.004 0.004 0.004 2001 2,4,5-TP Silvex 0.05 0.001 0.025 2003 2,3,7,8-TCDD (dioxin) 3x10"g 5x10"9 0 e Thiobencarb 0.07 0.001 0.07 2000 Toxa hene 0.003 0.001 0.00003 2003 Chemicals with MCLs in 22 CCR §64533-Disinfectant Byproducts Total Trihalomethanes 0.08 -- -- -- Bromodichloromethane -- 0.0005 (zero) Bromoform -- 0.0005 (zero) Chloroform -- 0.0005 (0.07) Dibromochloromethane -- 0.0005 (0.06) Total Haloacetic Acids 0.06 -- -- -- Monochloroacetic acid 0.002 (0.07) Dichloroacetic acid 0.001 (zero) Trichloroaceticscid 0.001 (0.02) Bromoacetic acid 0.001 -- Dibromoaceticacid 0.001 -- MCLs, DLRs and PHGs for Regulated Drinking Water Contaminants Last Update: December 31, 2009 DLR PHG or Date c (MCLGI PHG TT TT a. A draft CA PHG of 0.0007 mg/L was published in 2009 b. For informational purposes only-no action needed at this time c. A draft CA PHG of 0.0005 mg/L was published in 2008 d. A draft CA PHG of 0.000013 mg/L was published in 2009 e. A draft CA PHG of 1x10-9 mg/L was published in 2007 f. Draft CA PHGs for individual trihalomethanes were published in 2009 ' OEHHA's review of this chemical during the year indicated (rev200X) resulted in no change in the PHG. "Surface water systems only EXHIBIT C Health Risk Information for Public Health Goal Exceedance Reports April 2010 Under the Calderon-Sher Safe Drinking Water Act of 1996 (the Act), water utilities are required to prepare a report every three years for contaminants that exceed public health goals (PHGs) (Health and Safety Code Section 116470 (2)[b]). The numerical health risk is to be presented with the category of health risk, along with a plainly worded description of these terms. PHGs are published by the Office of Environmental Health Hazard Assessment (OEHHA) as concentrations of contaminants in drinking water that OEHHA, using current risk assessment principles, practices and methods, considers to pose no significant health risk if consumed for a lifetime (Health and Safety Code Section 116365). This report is prepared by OEHHA to assist the water utilities in meeting their requirements. Numerical health risks. The tables that follow summarize health risks for chemical contaminants in drinking water that have PHGs and state and/or federal regulatory standards. The regulatory standards are maximum contaminant levels (MCLs). As defined in statute, PHGs for noncarcinogenic chemicals in drinking water are set at a concentration "at which no known or anticipated adverse health effects will occur, with an adequate margin of safety." For carcinogens, PHGs are set at a concentration that "does not pose any significant risk to health." PHGs provide one basis for revising MCLs, along with cost and technological feasibility. OEHHA has been publishing PHGs since 1997 and the entire list published to date is shown in Table 1. The Act requires that for chemical contaminants with California MCLs that do not yet have PHGs, water utilities will use the federal maximum contaminant level goal (MCLG) for the purpose of complying with the requirement of public notification. MCLGs, like PHGs, are strictly health based and include a margin of safety. One difference, however, is that the MCLGs for carcinogens are set at zero because the United States Environmental Protection Agency (U.S. EPA) assumes there is no absolutely safe level of exposure to them. PHGs, on the other hand, are set at a level considered to pose no significant risk of cancer; this is usually a no more than one-in-a-million excess cancer risk (1x10-6) level for a lifetime of exposure. Chemicals with MCLGs but no PHGs are presented in Table 2. The cancer risks shown are based on the U.S. EPA's evaluations. Please note that draft PHGs for dioxin (2,3,7,8-TCDD), hexavalent chromium, selenium, styrene and the trihalomethanes (THMs) have been posted for review and comment on the OEHHA web site at httg://www:oehha.ca.gov/water/php/index.html. These may be of interest to water agencies as an indication of the proposed direction of the OEHHA Office of Environmental Health Hazard Assessment Page 1 Water Toxicology Section April 2010 risk assessments, but are not required to be cited in communications with the public because they are not yet final. Health risk categories. The following information can be used for presenting the health risk categories in "exceedance reports." The health risks shown in the tables are based on long-term exposures to low levels of contaminants as would occur with drinking water (unless otherwise stated), rather than high doses from a single or short- term exposure. The potential health effects are the most sensitive adverse effects that occur when chemical exposure reaches a sufficient level and duration fo produce toxicity. Health goals that protect against these risks also protect against health risks that would occur from short-term exposures. For most health risk categories, the specific health outcome or the organ or system that is affected is also given. The health effects are given in nontechnical terms when possible, and the categories are described below. Acute toxicity- adverse health effects that develop after ashort-term exposure to a chemical (minutes to days). Subchronic toxicity- adverse health effects that develop after repeated or longer-term exposures to a chemical (days to months). Carcinogenic -capable of producing cancer. Chronic toxicity -adverse effects that usually develop gradually from low levels of chemical exposure over a long period of time (months to years). Developmental toxicity -adverse-effects on the developing organism that may result from exposure prior to conception (either parent), during prenatal development, or postnatally to the time of sexual maturation. Adverse developmental effects may be detected at any point in the life span of the organism. The major manifestations include: (1) death of the developing organism, (2) structural abnormality (birth defects), (3) altered growth, and (4) functional deficiency. Neurotoxic -capable of adversely affecting or destroying parts of the nervous system or interfering with nerve signal transmission. Effects may be reversible (for example, effects on chemicals that carry nerve signals across gaps between nerve cells) or irreversible (for example, destruction of nerve cells). Reproductive effects -the occurrence of adverse effects on the reproductive system of females or males that may result from exposure to environmental agents. The toxicity may cause changes to the female or male reproductive organs, the regulating endocrine system, or pregnancy outcomes. Examples of such toxicity may include adverse effects on onset of puberty, egg production and transport, menstrual cycle normality, sexual behavior such as sexual urge, lowered fertility, sperm production, length of pregnancy, and milk production. Office of Environmental Health Hazard Assessment Page 2 Water Toxicology Section April 2010 The tables further note whether the health risk category is based on human or animal data. Data on health effects of toxic substances are usually obtained from studies on laboratory animals. For more information on health risks: The adverse health effects for each chemical with a PHG are summarized in each PHG technical support document. These documents are available on the OEHHA Web site (http:!/www.oehha.ca.gov). Also, U.S. EPA has consumer and technical fact sheets on most of the chemicals having MCLs. For copies of the fact sheets, call the Safe Drinking Water Hotline at 1-800-426- 4791, orexplore the U.S. EPA Office of Ground Water and Drinking Water's home page at http://www.epa.gov/OGWDW/hfacts.html. Office of Environmental Health Hazard Assessment Page 3 Water Toxicology Section April 2010 Table 1: Health Risk Categories and Cancer Risk Values for Chemicals with California Public Health Goals (PHGs) cancer ~ 0.0045 ~ NA5 ~ 0.002 ~ NA Aluminum chronic toxicity 0.6 NA 1 NA (increased serum aluminum level) (human data) Antimony chronic toxicity 0.02 NA 0.006 NA (shortened lifespan) Arsenic cancer 0.000004 1x10-6 0.01 2.5x10-3 (4x10-5) (one per (2.5 per million) thousand) Asbestos cancer 7 MFL 1x10-5 7 MFL~ 1x10-6 (fibers (fibers (one per >10 >1p million) microns in microns in length) length) Atrazine cancer 0.00015 1x10-5 0.001 7x10-6 (seven per million) ~ Health risk category based on experimental animal testing data evaluated in the OEHHA PHG technical support document unless otherwise specified. z mg/L =milligrams per liter of water or parts per million (ppm) (PHGs are expressed here in milligrams per liter for consistency with the typical unit used for MCLs and MCLGs.) s Cancer Risk =theoretical 70-year lifetime excess cancer risk at the statistical upper confidence limit. Actual cancer risk may be lower or zero. Cancer risk is stated in terms of excess cancer cases per million ~or fewer) population exposed for a lifetime. MCL =maximum contaminant level. e Non-linear approach used for alachlor risk assessment, no cancer risk assumed at the PHG level. s NA =not applicable. Noncarcinogenic, or a cancer risk cannot be calculated. The PHG for these chemicals is set at a level that is believed to be without any significant public health risk to individuals exposed to that chemical over a lifetime. ~ MFL =million fibers per liter. Office of Environmental Health Hazard Assessment Page 4 Water Toxicology Section Apri12010 Table 1: Health Risk Categories and Cancer Risk Values for Chemicals with California Public Health Goals (PHGs) Barium chronic toxicity 2 NA 1 NA (hypertension) Bentazon chronic toxicity 0.2 NA 0.018 NA (clinical, body weight, liver and intestinal effects) Benzene cancer 0.00015 1x106 0.001 7x10-6 (leukemia) (seven per million) Benzo[a]pyrene cahcer 0.000004 1x10-6 0.0002 5x10-6 (five. per hundred thousand) Beryllium chronic toxicity 0.001 NA 0.004 NA (gastrointestinal lesions) Bromate cancer 0.0001 1x1.0-6 .0.01 1x10' (one per ten thousand) Cadmium chronic toxicity 0.00004 NA 0.005 NA (kidney effects, human data) Carbofuran chronic toxicity 0.0017 NA 0.018 NA (enzyme inhibition, blood chemistry and testis effects) Carbon cancer 0.0001 1x10-6 0.0005 5x10-6 tetrachloride (flue per million) Office of Environmental Health Hazard Assessment Page 5 Water Toxicology Section April 2010 Table 1: Health Risk Categories and Cancer Risk Values for Chemicals with California Public Health Goals (PHGs) Chlordane cancer 0.00003 1x10-6 0.0001 3x10-6 (threeper million) Chlorite chronic toxicity 0.05 NA 1 NA (anemia) and neurotoxicity (infants and children, human data) Copper acute toxicity 0.3 NA 1.3 (AL)8 NA (gastrointestinal effects in children, human data) Cyanide chronic toxicity9 0.15 NA 0.15 NA (no clinical and histopathological effects observed) Dalapon chronic toxicity 0.79 NA 0.2 NA (kidney effects) 1,2-Dibromo-3- cancer 0.0000017 1x10-6 0.0002 1x10A chloropropane (1.7x10-6) (one per ten (DBCP) thousand) 1,2-Dichloro- chronic toxicity 0.6 NA 0.6 NA benzene (o-DCB) (liver effects) 1,4-Dichloro- cancer 0.006 1x10-6 0.005 8x10-' benzene (p-DCB) (eight per ten million) s AL =action level. z Cyanide: Acute toxicity of concern is respiratory arrest. Long-term exposure allows for detoxification. Office of Environmental Health Hazard Assessment Page 6 Water Toxicology Section Apri12010 Table 1: Health Risk Categories and Cancer Risk Values for Chemicals with California Public Health Goals (PHGs) Health'Risk Caiitornia Cancer 'Califorrfia .Cancer 1 Chemical Category PHG Risk3 MCL4 Risk @ (more specific (mg/L)2 @PHG (mg/L) California :information in MCL " parenttreses7"; 1,1- cancer 0.003 1x10.6 0.005 2x10.6 Dichloroethane (two per (1,1-DCA) million) 1,2- cancer 0.0004 1x10.6 0.0005 1x10.6 Dichloroethane (one per (1,2-DCA) million) 1,1-Dichloro- chronic toxicity 0.01 NA 0.006 NA ethylene (liver effects) (1,1-DCE) 1,2-Dichloro- Subchronictoxicity 0.1 NA 0.006 NA ethylene, cis (kidney effects) 1,2-Dichloro- Subchronic toxicity 0.06 NA 0.01 NA ethylene, trans (liver effects) Dichloromethane cancer 0.004 1x10.6 0.005 1x10.6 (methylene (one per chloride) .million) 2,4-Dichloro- chronic toxicity 0.02 NA 0.07 NA phenoxyacetic (liver and kidney acid (2,4-D) effects) 1,2-Dichloro- cancer 0.0005 1x10.6 0.005 1x10.5 propane (one per (propylene hundred dichloride) thousand) 1,3-Dichloro- cancer 0.0002 1x10.6 0.0005 2x10"6 propene (two per (Telone II®) million) Di(2-ethylhexyl) developmental toxicity 0.2 NA 0.4 NA adipate (DEHA) (disrupted development) Office of Environmental Health Hazard Assessment Page 7 Water Toxicology Section April 2010 Table 1: Health Risk Categories and Cancer Risk Values for Chemicals with California Public Health Goals (PHGs) Diethylhexyl- cancer 0.012 1x10.6 0.004 3x10-' phthalate (DEHP) (three per ten million) Dinoseb reproductive toxicity 0.014 NA 0.007 NA (uterus and testis effects) Diquat chronic toxicity 0.015. NA 0.02 NA (eye effects) and developmental toxicity (malformation) Endothall chronic toxicity 0.58 NA 0.1 NA (stomach effects) Endrin chronic toxicity 0.0018. NA 0.002 NA (liver effects) and neurotoxicity (convulsions) Ethylbenzene chronic toxicity 0.3 NA 0.3 NA (phenylethane) (liver effects) Ethylene cancer 0.00001 1x10.6 0.00005 5x10.6 dibromide (five per million) Fluoride chronic toxicity 1 NA 2 NA (tooth mottling, human data) Glyphosate chronic toxicity 0.9 NA 0.7 NA (kidney effects) Heptachlor cancer 0.000008 1x10.6 0.00001 1x10.6 (one per million) Office of Environmental Health Hazard Assessment Page 8 Water Toxicology Section April 2010 Table 1: Health Risk Categories and Cancer Risk Values for Chemicals with California Public Health Goals (PHGs) Heptachlor cancer 0.000006 1x10-6 0.00001 2x10-6 epoxide (two per million) Hexachloroben- cancer 0.00003 1x10-6 0.001 3x10.5 Zene (three per hundred thousand) Hexachlorocyclo- chronic toxicity 0.05 NA 0.05 NA pentadiene (HEX) (stomach lesions) Lead chronic toxicity 0.0002 3x10$ 0.015 (AL) 2x10-6 (neurobehavioral (PHG is (two per effects in children, not based million) hypertension in adults) on this and cancer effect) Lindane cancer 0.000032 1x10-6 0.0002 6x10-6 (y-BHC) (six per million) Mercury chronic toxicity 0.0012 NA 0.002 NA (inorganic) (kidney effects) Methoxychlor reproductive toxicity 0.03 NA 0.03 NA (vagina, ovary, uterus and hormonal effects) Methyl tertiary- cancer 0.013 1x10-6 0.013 1x10-6 butyl ether (one per (MTBE) million) Molinate cancer 0.001 1x10-6 0.02 2x10.5 (two per hundred thousand) Office of Environmental Health Hazard Assessment Page 9 Water Toxicology Section April 2010 Table 1: Health Risk Categories and Cancer Risk Values for Chemicals with California Public Health Goals (PHGs) Monochloroben- subchronictoxicity 0.2 NA 0.07 NA zene (liver damage) (chlorobenzene) Nickel developmental toxicity 0.012 NA 0.1 NA (increased neonatal ', deaths) and possible cancer risk Nitrate acute toxicity 45 as NO3 NA 45 as NO3 NA (methemoglobinemia, human data) Nitrite acute toxicity 1 as NA 1 as NA (methemoglobinemia, nitrite- nitrite- human data) nitrogen nitrogen Nitrate and Nitrite acute toxicity 10 as NA 10 as NA (methemoglobinemia, nitrogen nitrogen human data) N-nitrosodimethyl- cancer 0.000003 1x10"6 --- --- I amine (NDMA) Oxamyl chronic toxicity 0.026 NA 0.05 NA (body weight effects) Pentachloro- cancer 0.0003 1x10.6 0.001 3x10.6 phenol (PCP) (three per million) Perchlorate subchronictoxicity 0.006 NA 0.006 NA (thyroid and reproductive effects) Picloram chronic toxicity 0.5 NA 0.5 NA (liver effects) Office of Environmental Health Hazard Assessment Page 10 Water Toxicology Section April 2010 Table 1: Health Risk Categories and Cancer Risk Values for Chemicals with California Public Health Goals (PHGs) HeafthRisk - California Cancer Caiifornra Cancer Chemical Category PHG Risk3 MCL4 . ~ Risk @ (more specific ~ ~ (mglL)~ @PHG ~ {mg/L~ Ga6fornia `.information in MCL :parentheses). Polychlorinated cancer 0.00009 1x10"6 0.0005 6x10-6 biphenyls (PCBs) (six per million) Radium-226 cancer 0.05 pCi/L 1x10-6 5 pCi/L 1x10 (one per ten thousand) Radium-228 cancer 0.019 pCi/L 1x10-6 5 pCi/L 3x10 (Combined (three per ten Ra22s+z2s) thousand) Silvex (2,4,5-TP) chronic toxicity 0.025 NA 0.05 NA (liver effects) Simazine chronic toxicity 0.004 NA 0.004 NA (reduced body weight) Strontium-90 cancer 0.35 pCi/L 1x10"6 8 pCi/L 2x10-5 (two per hundred thousand) 1,1,2,2- cancer 0.0001 1x10-6 0.001 1x10-5 Tetrachloroethane (one per hundred thousand) Tetrachloro- cancer 0.00006 1x10-6 0.005 8x105 ethylene (eight per (perchloro- hundred ethylene, or PCE) thousand) Thallium subchronic toxicity. 0.0001 NA 0.002 NA (hair loss) Thiobencarb chronic toxicity 0.07 NA 0.07 NA (body weight, food efficiency and enzyme activity effects) Office of Environmental Health Hazard Assessment Page 11 Water Toxicology Section April 2010 Table 1: Health Risk Categories and Cancer Risk Values for Chemicals with California Public Health Goals (PHGs) Health :Risk California Cancer California Cancer Chemical ~ ,Category' . Pl•tG Risk3 ~ IVICG` ~ Risk @ ~mbre"specific jmg1L)~ ~ PHG ;;, (mg/L) ~ California ;information in NtCL _ parenthesesj, " Toluene chronic toxicity 0.15 NA 0.15 NA (methylbenzene) (liver and thymus effects) Toxaphene cancer 0.00003 1x10-6 0.003 1x10-4 (one per ten thousand) 1,2,4-Trichloro- chronic toxicity 0.005 NA 0.005 NA benzene (effects on adrenal (Unsym-TCB) glands) 1,1,1-Trichloro- neurotoxicity (structural 1 NA 0.2 NA ethane changes), reproductive toxicity (fewer offspring), chronic toxicity (liver and blood effects) 1,1,2-Trichloro- cancer 0.0003 1x10-6 0.005 2x10.5 ethane (two per hundred thousand) 1,1,2-Trichloro- cancer 0.0017 1x10-6 0.005 3x10-6 ethylene (TCE) (three per million) Trichlorofluoro- chronic toxicity 0.7 NA 0.15 NA methane (liver effects) (Freon 11) 1,1,2-Trichloro- chronic toxicity 4 NA 1.2 NA 1,2,2-trifluoro- (liver effects) ethane (Freon 113) Office of Environmental Health Hazard Assessment Page 12 Water Toxicology Section April 2010 Table 1: Health Risk Categories and Cancer Risk Values for Chemicals with California Public Health Goals (PHGs) # Health ;Risk California Cancer California Cancer Chemical ,Category PIiG. Risk3 MCL4 Risk@ (more specific ~ ~ {mgat)~ ~ @ PHG {mglL} California.: informa#ion in MGL , ;parentheses) Tritium cancer 400 pCi/L 1x10.6 20,000 5x10-5 pCi/L (five per hundred thousand) Uranium cancer 0.43 pCi/L 1x10-5 20 pCi/L 5x10-5 (five per hundred thousand) Vinyl chloride cancer 0.00005 1x10.6 0.0005 1x10-5 (one per hundred thousand) Xylenes neurotoxicity 1.8 (single NA 1.75 (single NA (effects on senses, isomer or isomer or mood and motor sum of sum of control, human data) isomers). isomers) Office of Environmental Health Hazard Assessment Page 13 Water Toxicology Section April 2010 Table 2: Health Risk Categories and Cancer Risk Values for Chemicals without California Public Health Goals Health Risk Category1 U.S. EPAi .Cancer Galifornia . Dancer Ghemical (mots specific , MCf;G~ ~ : Risk3° MGL4 .Risk @, inforrnation in . ;(mg/L) ~ @ '~ , ~ (mg%L}.. Galifornia; parsnthese5), MGLG MCL Chromium (total) chronic toxicity 0.1 NA 0.05 NA (stomach, liver effects), immunotoxicity (allergic dermatitis) Dioxin cancer and 0 0 0.00000003 1X10-5 (2,3,7,8-TCDD) reproductive effects (one per hundred thousand) Selenium chronic toxicity 0.05 NA 0.05 NA (hair and nail changes, skin lesions, blood effects; human data) and neurotoxicity Styrene chronic toxicity 0.1 NA 0.1 NA (vinylbenzene) (liver, kidney and blood effects) Disinfection byproducts (DBPS) Chloramines acute toxicity (irritation) 45 NA none NA and chronic toxicity (stomach effects, anemia) Chlorine acute toxicity (irritation) 45 NA none NA and chronic toxicity (stomach effects) ~ Health risk category based on experimental animal testing data evaluated in the U.S. EPA MCLG document or California MCL document unless otherwise specified. z MCLG =maximum contaminant level goal established by U.S. EPA. s Cancer Risk =theoretical 70-year lifetime excess cancer risk at the statistical confidence limit. Actual cancer risk may be lower or zero. Cancer risk is stated in terms of excess cancer cases per million (or fewer) population, e.g., 1x10 5 means one excess cancer case per million people; 5x10-5 means five excess cancer cases per 100,000 people. ° California MCL =maximum contaminant level established by California. 5 Maximum Residual Disinfectant Level Goal, or MRDLG Office of Environmental Health Hazard Assessment Page 14 Water Toxicology Section April 2010 Table 2: Health Risk Categories and Cancer Risk Values for Chemicals without California Public Health Goals :Health Risk Category U.S. fPA`:- Gancer .California Cancer i ~(more.specific" ~ MGLG~ Ris{c3i~ ~ MCL4 Risk @ Chemical.. information in (mg/L) @. ; (mg/L) California= parentheses}, MCLG MCL Chlorine dioxide chronic toxicity (anemia) 0.85 NA none NA and neurotoxicity (infants and young children, human data) Disinfection byproducts: haloacetic acids (HAA5) Chloroacetic acid chronic toxicity 0.07 NA none NA (body and organ weight changes) Dichloroacetic cancer 0 0 none NA acid Trichloroacetic chronic toxicity 0.02 0 none NA acid (liver effects) Bromoacetic acid NA none NA none NA Dibromoacetic NA none NA none NA acid Total haloacetic cancer none NA 0.06 NA acids Disinfection byproducts: trihalomethanes (THMs) Bromodichloro- cancer 0 0 none NA methane (BDCM) Bromoform cancer 0 0 none NA Chloroform chronic toxicity 0.07 NA none NA (liver and kidney effects) Dibromo- chronic toxicity 0.06 NA none NA chloromethane (liver and kidney effects) (DBCM) and neurotoxicity Office of Environmental Health Hazard Assessment Page 15 Water Toxicology Section April 2010 e MCLs for grass alpha and beta are screening standards for a group of radionuclides. A corresponding PHG was considered inappropriate because risks vary for the individual radionuclides covered by the screening level; see OEHHA memoranda discussing the cancer risks at these MCLs at h tt p: //www. o e h h a. ca. g ov/water/ p h g/i n d e x. h tm I. ' pCi/L = picocuries per liter of water. Office of Environmental Health Hazard Assessment Water Toxicology Section April 2010 Page 16 Table 2: Health Risk Categories and Cancer Risk Values for Chemicals without California Public Health Goals CITY OF SANTA MONICA WA"iER DIVISION ~aar~e~r~a a~~ F'~-i ~r~ C.Srir~l6ie~~ a~~~ Cl~a~l~-t~ Fi~st.al~ts ~~~° ~t7CP~ EXHIBIT D 7 s t ,>ii 9 i3 LOCAL '. I U ~ ~~ `~~(f ~ (i ' ((I P ~(it til i ~nEi~ ~ s ti MAJOR SOURCES (is ,i(~~'p~~sssl C~,~~' WELL WATER IaI SM WELL Ai IhI i+ ~s~{(~~,I~Pk'ty~ I(i ~+I!( ~~~ ~}~y ~' ~~ '~i~i+ IN DBINKING WATER ~,~~ ~~tE@ {~t t t ~E+~ i~''"~'~~~~si~Yi ~+~ ~ sI~IIif~, ~~~i~~R ~f~~~l¢~IS~`.aiS~~l,~fl Parameter IEEi. ~Nii.El€ Arcadia Plant: d.,.~:6 mnl tftiPykdii, (tllsri,Idr{~O~fZi l~nFi i,.lr. IC16x 9r:`ri c arif I~~'i9~~'~i'i,~5.li~'i131~I~I~s3I,I '71 islyhiii i+~ fi t(ss l s s ~s ss ls: ! y~~t{ s ts. ps ° 03 ~ 'i!i (n)il ( 3 lil s sag { + E ss s~61 FEF {E.. Maximum Turbidity lNTUI I10 I!(Ippp 31s N/A N/A N/A N/A ni'Ob sl 3'~~¢i/ gQ~ 1 ° ~,~.{ Ir{ f(~It I l;~ s€ ikl~ i((i (,~~~ p~i(~( ( I t~ 3'3 1+~ (( ty( + k(t (t { : III+II it Soil runoff i S i ss s¢ i ' Liss (s { k`!s`( { ( i (l I t` s~99i sssSq s({(ti ((s i( (i {~((I I( it Microhialoaical ~~j ~{ + f lIR {..s ({II(~{Eli(~IIGji(llhiliiiii~~~i((i~3s'~~~~ii~j( Total Coliform Bacteria l { n] j78,3' l{{= ~7;~7~{tti,~t~. tr Ettpeh~pgp~~p ;t ~''i3 jf tr;~+t};7{r~ t }~ j t 7G S II s I t!('+ t 7d'tyJ i~~it {1~fli( 1{lll+i{{i z {P ~g4~~i~t3g~!lGIIE!I!{iRl7![fI'f~ulfGEtp9[kL'G4i~~7~.., 41 ~~~~~}'1)~y~~sii'~~~~ISj~S~~~~~~+~~~`~I~~+~{~~~~~~~f+~~i~~~l'+~Il~i€i3! (t~I+S I{{i. Naturally present in [he environment (%positive samples/month) ~~s~+~~~~:~~ Isi{ „j ii Kill ii ii) (l~9:j~l ~i 131~I ~.i. i~lyss s t }st t°~ i3~ ` t ,, a ...+ tnirtr7~i ttyt f 7 t ~ i pal t 5 fg { Fecal Coliform/E. Colt ~~3{ff1~3.I 3 s ~ ~~j?y{'~jgiq;tt„~H',5.t3 1i ri8G9€f8+lf~ dP7lttdil~~r"'~,~~~h'~Et"~P~~~Ei~t~(({I5(f':.'~(iN~~~ ° t ~"~( is I~ r~L~ ~ i 1 k~ + S I ss E { t ; ; l 1ss l 1 Human and animal fecal waste Or anic Chemical ~ (; ~l'i~l,l( j;hP sl sI0 11U Iii~ij 3 sill ~ (ttt~ ss i ;i (tl t t ids s~+i{4~i~ g ~fS,{{.~'{~°~'s EE (+ I {~+s'jt I Et is14 s4 ~{E~{IftI(I'+i(Ihil (Ji~i~Ii iJ ~tli~~ Methyl tart-Butyl EtherIMTBEI Ippb) 1 ~ P-# (i ill,. ND ND'. t ND ND ~: ~j~ t} 4s ~,~{IIS{I {II NR(+(i{i ~ i~ ~~(~j1((+I {Is{islli~!~ Leaking underground storage tanks f i ({ I t~ (~ tl I((~~~ ~) ~~l ~ 3s~ Trichloroethylene Ippb) {{ i , ~jtl~,~ 65 ND 1.2 NB ND It"li ~-~ slt~it N11:i ~i74~i~~pi sIII 7~~i7~i~~iq(' i~i ijssAls it Discharge from metabdegreasing sites [1 ssl( (I I i(i is s 113 i+ 4 si s s ssss Disinfection lk { ii((;( (i ~~I((Iili Il dili~~~i~j9~i~~I~I~i ~il~~i ~ ] ssy) l i i{i sss 7S~ . ~~{+ € p t(t O I~~i Iy~l~lii islsiis i s1 {il ss ssss +& l{{i Byarotucts&Residuals j(,9 }3 ' ij idi Ei i~I ilj j~js i s, 3.t r.: ~ { t ti g( Ii IIis` k ii ~3I~ I~ 9 {j 1' s p t ~ t 'tort ; r rI'(~1 ,~ , tr t bi, t i~'~i0~ ~~) E Total Trihalomethanes Ippb) ! ~ ~{~~ ~{ l s lkl I{ +L ii= ~ ~ti' ~ ~i ~~j( ; ( k~ , I ! j g$~{ ~i ~{ ~~ S~s~~i G~~li ~isi7s By-product of drinking water chlorination Halvacetic Acids lDPbl t~~~~° ~~,~~" ~ ~{~ ~j. (~~~p;' ~ 91~ & I ~ ~ 3:i ~t~ ~ 'Ih ~~~~(Ih~l~ai,,. BY'Produci of thinking water chlorination i I~~~~ ~~ ~~pppp~~, 7j7$yy~~s d { E p t {~ ~ '(i I i (i ij Total Chlorine/Chioramines lpPml ~+j~L~ ~I~ ~~ i~i ~~~~ ~r~r ~~ ds l;il tl ~ I Is~~i~~~~~~ ~,.+~ i i ~~~~~~~3i+jJ II+~ s',. Drinking water disinfectant added for treatment { EE~~~ ,p~ l ~~ {jI sslSs{{ ijgl ii lsi "sIl ( IINsI i Bromate Ippb) 1 ,!j(E'IC '~I NIA N/A: N/A N/A s,. t¢ i i i ! 1 ~I,°j = C#~ f ~s Rl~is i?~G1i ~q ~ ~j~(~i;~a~}f~+ x!s I iIs 6Ij ~ i~.is~I s~ (j ss III 33 ssss, sl t s{s BY product of drinking water ozonation (( i ( ~ (~iil i{~ii++ip~! 1 t i i t(' t( t14sliti(,i~ Inorganic Chemicals ~ it L( { : ii ~) s~I((iJ is~i ~~ il1ls st I tsn{+ { i ~{ {i ks' lI i is i s I 'j~ i~i sniisP! 1 ~ ! { tttt F t.tf t i t~~t Ei (s~I(~I ~li ~~I~ Aluminum lppml s~, j 006 006'. NO ND 4~~i (Q,tP ~kl 3s D:b 14s y ti ~8{lit si[~s f~'I (~ii lei I Ills Erosion of natural deposits; used in water treatment process Arsenic Ippb) ~ ~~,~ + 14 0.9-1.9 07 07 Il~~jjj?~~~', °f~F}~5{x+.I jifiypll~i(~Illit~i ~~~Is~~~~~~~~~~13 ~~~~~'~~I~s~'. Erosion of natural deposits Barium lppml (~ ~ s~~s -005 0.05'. 005 005 _,lNlks.s d~i'{I~. t(i("(~({I: ~{il~i(P slit ass Rj s3s siisi Discharge from oil and metal industries; Erosion of natural deposits ~(~ l 3 ~ s s s Is' ~ 7~~1~ s iP S ty~y ry l er ~,y~s{~' I' ~ { {ff a~#I h l H +~„{(~ sj ss($ ~ ~(~ ~ ' s s i s s. Copper lei lPPml ~ ~~~li ~i `+ s{ id?Giil~l~~II~~~~~~Iii~h~ilht~~~~~II~({PII ,~hYS~~RY~~~~T~NEP,,.i}S•~tl~~igiF~y~K~~'~y~,q~~~~ d ji n.t) Corrosion of household Plumbing systems ~EI ~~~ddd {, ~, i ;t; ,~91 t) t s 1 s t g, s; ; tt gsE~~'t t't tiCt i~i (' Fluoride lpPml ~~ ~I{ ll s( tsj` qE l02 0,2:-0.3 ~ 0.3 03 :q, tli (ii Ii l;~ik ~' islsisA Ns)ss,ssss Ri UUU ~{E,i sj~i s~~i l( Erosion of natural deposits Fluoride After Treatment lPPml { {l ' '( ~ { i° l Fy ~ m r t' ~"~~„{~j S t ~~}i~ {'~331~ Is } sI j ~'' ` ~ ~j ss s ~$'s s `{st Ntli({j~(I l {lIC+~~~~~IdIH~II~Y a~(d~~~~~,97~~,.,tt~~ ~ ~ ~~j '~i` ~'i (~~~ii~~~lU{ Wateradditive for dentalhealth Lead lei Ippb) >l ~ ~ i,tl ~ s, "I F i;s;, ~is v t~~~i ~~~',a~~} ~~:+ ~~!~~1 ~~ I17S~Iiv sssinir~ Corrosion of household plumhin9 systems Nitrate las N lppml sl ~ i' s i !' 28 25-3.1 3.9 38 40 n; ~~~s~ L~ppiit (i j ll~i is I ~hii sis ; s{ i Runoff from fertilizer use; Leachin from sewat e; ~I ~ I1~.s9s [ t s t¢ip I tp jl { (ilj i~L1pp t ~s s 9 J ~tt~s~s,~~~j i33 {~~~~~p~~ Ip{p0 Ili ~ t ttt ir(ii(~ri jl~~i i~~3 i~Iiiii,i~Li~(isl sl{s! l+ ! i st(. Erosion of natural de osits ~~~ ~ll~ ~ ~~~! {((~ {~ i ~~~i ~~ ~ i~ ,l(i (3 (~~ E) li) )till ( ~ ! ~ j"i I( l ili+ > ~~ { { {'i i`~{ii p Perchlorate Ippb) sE E{'. {{ v s~E{ ~s dE ND ND ~ ND ND ~i i ~ ((jai is ~. isi is 71 ~{it {~£ {i ~is ((I GIs ((( ii i77 7s Intustrial waste discharge ~~i It s i~~~~ ~I~~~ € { E~j ~ i~3~ (i ~ s (ssss hs { s[s {~ slt~s s".iii ~llll~~Cijjl Redidnuclidas { t~. {~l{{ s ~I'~I ~~~ { i (~i~ ii{ Its ~s sl(/b~7LR t t t it+k Nt ~ a{s~~i t 3 i 1ji t ( ~J s s (t)ilt I i~sis) si ! s s (;ts jss i s(~I s (~l+s(I) Alpha emitters PCl/II >* {~~ss ~~:- NO ND. ND ND ~'171~,~~i~I+t l(sst ={~ss {{ s{(`i Ss(~j(iii'i~~~ ~~ si~ix~~j~~~~~~~~~ (': Erosion of natural de osits ~il i,;~! sqs e, +t+'('is stt ll i~i (i~ t{~i(i iii rsf I .~ ~~ p Beta/photon emitters lpCl/II ;~~,i 11~P~,~'1 ~W ~' N/A N/A, N/A N/A ~,~ssts(l {tI i Iii}i~i~~l~ ilil~lkl~ p{1 p~ test {l{Y ~~s' ~~ Ls~l i (sli ill n'~~~(~iii~l il~~tl.i~~ll l{s3 ~b ~~(f7p tr~r7r~i}s. ( Decay of natural and man-mate deposits Combined Ratium lPCi/II S~13~1~~~13,;~,~t,.~~ sll~~ ND NDS 078 078 r(`s,{~s~~{{iii ~~iii i;,iiis ii jSS7I~~(~iSss +~s sNA'st`{i~{i~s~iP}I1', Erosion of natural deposits Uranium lpCi/II ~ ~~ d 00 si s t i I ~ If ii i s s 3 31; 33~Ita i28 27-3,p 080 080 I, ({~} Ii~(~Ir 4~lli+l {'~l9 fjp ("~Eip'(i 9 ih Erosion ofnatural de osits I~,~lr3,~~~: ~~E~,IIiE!'~i,~l(,~, ,~~i;i('~~j El'hti( {(n.IL,(i,~°u~1...,,xJd°,,,t„tmil~i i~u;E;li~~~x'll'7:a~j~ p KEV T® ABBREVIATIONS Primary Orinkiny Water StandaNs = MCLs for contaminants that affect health along with (hair monitoring and reporting requirements, and water treatment requirements. PNG =Public Nealth Goal, or the lave) of a contaminant in drinking water below which them is ne known or expected risk to health. PHGs are set by the California Environmental Protection Agency MCLG =Maximum Contenninent Leval Goah or fie lave.) of a rontnminam in drinking water below whirh Chera, is no known or expected risk m health. MCLGs are set by the U.S. Envirm~mental Protection Agency. MCL= Maximmn Cnntamiuant Laval, nr the highest level of a contaminant that is alloweA in drinking water. Primary MCLs are set as close to the PHGS'lor MCLGSI as is economically and technologically feasible. MRULG =Maximum Residual Oisinlectan[ Laval Goal, or the level of no expected risk to health. MRGL.: Maximum Residual OisinfectantLevel,or [he level ofatlisinfectant added for lal=: FOr 2gy], the Arcadia well water treatmen[plant treatedablend of 45%well water water trea[mentthal may not he exceeded in me ronsumer's tap. anA 55% imported surface water. N/A =Not Applicable tb1= SM WeIlA1 is pumped'mto a transmission lion, is blended with Imported Surfacx AL=Action Level, or the concentration afacontaminant which, when exceeded, Water and enters the system at lyth Si. &Itlaho Ave. ttiggers treatment or other requirements which a water system must fallow. Icl = We are not required to test for every parameter each year. If indicated, data is NS=No Slandartl fromaprevious year. NU = Manimretl IDr but Nat Ua[arted Idl =Two consecutive Total Cnliiorm-positive samples, one of which contains Fecnl NTU=Nephelometric TUrbitliry Units-used to measure cloudiness of drinking water. Coliform/E. Colt wnsti[u[es an acute MCL violation, NO Violations occurred for 20g]. ppb=parts par billion, or micrograms per li[xr lpG/g lei=The MCC has been replaced wishatreatmenl technique requiring agouties to ppm =parts per million, or milliymms per liter Imylll optimize corrosion control. Results given are tram first tlmw, at-thetap monitoring pCi/1=picocuries per liter performed every three years. "=secondary standard; <=less than tl1= Fluoridation began tale November Z-g]; data is for December only. Per additional vwater quality questions, contact M. Cardenas, Principal 4PVater Cf'temist at 31 Q-826-6712 CI"t"Y OF SANTA MONICA WA~TE.R DIVISION u ~r-~ cs~ 1-~~rr~~lry ~~~ia~Icsr~c~ ~t~;w ~a~li~~ F~~~~it~ fca~° ~C&C3 a ~~3 ~i'~ ~ ~° 3u1~113Ii~ I1(+{ °' LOCAL t{Q~ i ! ~NIPbRY i'1 d i + + 4 ~ i u ,; i i F' ~ i j I ~ I li~lPO F it i~{) j I) MAJUR SOURCES 1 ~ ~ +~(~ y~('~~~ WELL WATER Ia) SM WELLN1161 i IMF W`f~Rilii °ill~ Ili) ~+~N~~4~1j, Parameter ~ i~~ii~j+ {+ I(,~,I ~ ~~ A.G~'; ~i ( i Ili ~~ A~` A#~~ + 4a~+p~e~il IN DRINKING WATER 1 13 ! Arcadia Plant , t NIA higt(!T(I fsI~t`4PI (IIII I~Ip,IULd ~yp>y ~,f 1{~+{ I~ ';lph tha'p Ii;'~' __....... 1~+. ~~~~~~I~I Average flange Average'. Rangy i.M~}{~Q51!,i~7!,:.:Iii.~lt@~1~,+,~af.47ff"j(ItiAlt~~iliiP~~eh~~OpB~~ij it ~ {Q{ i;df~l~ ~p{#Yii1~9i iij~ ~id p(+~i31i i' 11 tty h tti ~~~i~i(~{j~I~~Ihi~~~Ilili; i~j~il~~1ij Maximum Turbidity INTUI ~i ~ }~~ N/A N/A N/A N/A S (!' IQ i i i 1~7#ajd.KU;§ ~ Q ~¢ (+ II ij~q~o-~u~p ' ip l (i (~~Ijili{ Sail runoff +' Q,'1 ( 7 ,} j I III;!dpp{'III{ I I. !I t4;r 14s E I 1 i l i k Illy t ~3 i I~Iii I1 I {i~ ~I ~ j `P) I III i III, Microbiological ~ } E (((~Es '; iii iii ~ ++ + s F a tssi iji il~i; (i i I }~~ ~ ail I i 'i .l I~ II)11i Total Coliform Bacteria I ~ IESs€'" V~ ~„FPFaNtiE°=b ~ i~l+' ~' 1 ~'''u ++~(; 44~~'"P$+{j~'i~jE;'(il(#~s(~{Et{ v(^.(ii'~ ~}+ijit{~;'`ilsj ~ji, iilji~IS~ Naturally present in the environment ~ ~ p~p~, ? i p E ~~L,dE~~~~h~~s ~~:,~Pdb~ah~ ~ ~,>~`>~~I ~i t~~j(~~~ ~q~ ~ ~ ~ I h ~ ~~~~t { ~~~~ i ~ ~ ~ € (C ~ I%POSitive sam les/month) S, , ~~ ~ EI sE ~ElI; Eapc r 4"E"! ~~Tn n~ i ° y! c~au~BF ~ ~(}si{{nil+,i{{t3'3i+=i,~I3jl j! it il~~{sl :I i-'k{d# {~ {3II i}z}lt's`s4s i :i(~~{) fecal Coliform/E. Coll iOE,{IE~{{t r~ ~~ ~~3I ~,49'Cl~l~~1Q81~18{BId~~{FN~6~3Iaai:ahi€i iEPOE;d~.+i,~F;~G~~tT{~~FIFt:LTIy~ ({~}~n{~+ri ,~ °J~~~d iEt °i,# ~~ 41 (~(€ ii;( ~` 4,1 I, ~, ~~!° I~I~I ~~~'~~~~~ ~1~.. ~{51 +1~}~~ly~~{ T ISRSi~+ IE ~~${~;I #~ (~ ~ !~ Human and animal fecal waste Drnanic Chemical i~Iiil i((Ij'y°1~1°' i+S 11~1i 3; I I'I'I in it d~iil3;i lif! ~'I ~ii ill v~~~3+il ~s4'+4' ..I i'. i(; IE~:°,°~1yE3+siiI13~33 +3 ~'Ed 3i ~ ii s ~tl ~~ II t I I) IIII jil I ~i sjii;j~ i+ i ~ iiri{i:~i + Methyl tart-Butyl EtherIMTBEI IPPb) ° 1 ~5E °IEi11'p33 + NO N0 ND ND i+~ !N ~ ilia iIi41il {i Ilr~Dl tl_, ~{ i+ t + iii 1~~~9,g~ I~gt~~i~il~~~~~~E~I 0.4 ND-1.4 ND ND ~ s 4fd6 is(Ijlki ~illlflll~Iljiii Ii~ai+i+i M~s Ott Ss si, II Leaking undergroundstora9etanks Trichloroethylene lpp6l 1iy ~, S~I iI !°'' ~ iS Illll i ! i~l~i,+li li ~D rq-i ; +4 Dischar efrom metal de reasin sites ~.°„E' ! !~1°v'I 1. (;i 33 € Isis ;I II((II ~~i it ( it i 11Iis +~i +i i ii s .3 f,I i. 9 9 9 Oisinfectian I IS° IS~e+i II `dI°i E~4.Eppp IE~ 3 E1~31i + I I (Gr i II III (i I~ 'n'•I ii i 113+ 6~ S;'~ 9191,E3~i3s ° 91,~~i3 F r 11 IIII I IIII ii null III + i i lit i. I ; i 6 roducts & Residuals ~ °°1 ~vl~p 3s~ 1i,1°, lpppgg 33 ~p,Iv IS~1 1 € ~~ i s ( I~ {n l) 111 (j Ij11 +~i) ~ 13I I11!i i { ;S 1i (I i;i ! ~ 1 VP ~ ~~;i,133a~i 1113 Ii3~i~1,3 33i ~3 3 3 33 + I,. I,:, v i to sit r, i,.. Nr,in.,;p,c .n." U i#i (t. .i{; j,, ~II i li ?•' Ill, iP+(, i++, i i it' iii ,Si Total Trihalomethanes lPPb) ~~i~'i=,,g ~ ~~31l!IiiI 1~~31~1iv s" 9.3r l(1 qq (3113? 3 9, v . ~~ t ~ i~i~"i ~! ~~ ~~ ~3}'sl~ i t3+.lpi 93 ~ ,~9 ~i~,~~ ~3e~i,,??i 3, 3 +~ I ~E31 ~ ~ xC~ F< ~1~8A {~ '~ 1311 l1 (I 33 „(61..,,~,~1~, ;' ~s",E'111"+I'ipj~Vi,+;~ BV-Product of drinking water chlorination Haloacetic Acids b ~: ~ ~ ~: I,dl°~+3~3iI,~ l . ~3~s i1sl' I+ .3 ~Il9 ~~'31III~,+I'!5 : Vii" 133 E, i,11~l ~, dt{i ~ + x ~ij#'j+' 1'~ III,I~g9~1'I ~ i~1;1~ I~;ua.i;;i„(;,~ (DPI ~.~ ,,i ~~~1.~ r~~i 110 ~+33: ~ ~~ 11 ',~33~"ilsl'~~1~Si`~i[3 ~°{ ~~ ;~,+P .(~}:~~#j1 #? ~~ ~ ~;31"!'"{,3~j31S;3I;(',{~l;lf+, I:ll';'i+€ B - roduct of drinkin water chlorination ,,gg r~ ~ {I 1 3 n tc y ~ 1 + i 93{ 13 i °+j' ~ ' i 'js iE I(; +E a h`H~~"= t'{ 3 ?i ~11 ~~ ~ i~3 33E+ s~~I+IE~€ l;'+71.i (ly~llp Y P 9 Total Chlorine/Chloramines lPpm) '.~~ `,45 1' ~°s ~ }, 'i(33~~ 1 ~ 1 (. i!! 393~3q ~ E~ f $¢k;~{ (' ~ j~'~'s13 9~ 9933~~3~ ~ ~ Ee h ( }~,,~11hh,g,g33 ~ii~~~ I Ili ~'I'E3~~„S~~r~~~b ~~~~I~~~t3: Ii339S~S~1,~~~lSI~R15*l~u~+~t64T'tfi~~g~&,~.f ~~~i1~i~{; Sibs+, ~!7 3~3i,~s~,1~1°l~ i°~qi{ail jl i 71+) Drinking water disinfectant added fortreatment Bromate lPPbl ~~NSi °~q4~9~'9I°?~~ ~~,1s (~13,~~ 1~ N/A N/A N/A N/A ~iiii'(}Ij(} !' ~~ si ! '1 plus j~iiili~ +;y+i; 911ji i, + ~ I ~+°; ~{" 1~ 1l ~31~19(1=1~1{~ i I~~i +++il s ii i t E 3liliii i (ii' i ii.ii iji ~j7~iill'oh nj3'i'(Ij i iii) I BV Product of drinking water ozonation Inorganic Chemicals - f 1I,§'i3~I~~~3°i~I(l° ~~ ie:l~ Ili ii i`si ++~ 4t s;ilG (s III IIIIIII it I i~ IiI ij~~~+I ynljs I '#, +,.3:11,3gqI+I 3 iii'iiii 3 I Isi iC•i IIII in jlii~ll~•I°i IIII Ili Aluminum lppm) 1~' F>ii li ~ ~~,~ 0.07 0.06-0.8 ND ND IIIOrShall g(jG+gQ6 i~~~i (tlti~Ag ., Erosion of natural de osits; used in watertreatment rocess L l a 3,3f3 t ij~i i( ~jI. i I 21 jail ~ P P Arsenic IPP61. ~. ~' ~ ~j ,l 1 7 1 4 -20 7 4 1 4 I IIII 1+ii i Ntl: ~..~ s I Mali I i) i i III~+i Iii iii (I~1~ijiili+ ij + ( Eroson of natural de osits ~.- ~(IL,~iA;y ii l~ i ( + ,Ll ilii.j~li~il l~ I~Iii 3~iii~1~1I+i p Barium lpPml t#.~ ' 0.06 006 007 OW Ill~ 2 kt ':a "(3 I NW ~ (; {L~~ ~ ( I. Dischar efrom oil and metal industnes; Erosion of natural de osits 3i"° tl !fl't mi r o„'u ++ s v~l~i+{'+Ei'~ v41~ H +li ° 'i~i I~71 IsSi~ + it:~~ 9 P CoPPer lei lPPml I,Q ~',I j tt ,~~ ~3~q~i~t ~~( ~ ' 1~ i~i; i. ihQs, ~~~.'ii~'ii!' li$$ ~~~qt`~ I.~l, s, (~~N~~I I(;~ii,i~i+i+ii++r{s Corrosion of household plumb+n9 systems Fluoride After Treatment IDPmI ..3 } '! + 1, itliv (+ ° i i{ S~ 1 ~3 3(i s c 1 s i i i S i ~ ; 1 r +. ~ ~}~}}I}I~ { ~ ~~~~jj?? 3 ~ ~~1~'i!i i {~~7~~'(+Iai {~ }~~{~}i~i 3 s~~ + ~ 41S°~+i +i isi Water additive for dental health Lead Ie11PP41 ~'{a°t; j' °t~ '~~~i `A~~~~fYli + ~ ]31i~Hlt'L~~II~d'+.IIEi`-~~4ti3g{'t`?'~ 1~~~~~~1113 ~~~~EE~11~I~j~Iliili +11~ Corrosion of household lumbin sstems ~(~ ~ ; 7Fl h r 11 ~1{iS~Lh S'i ~G ii It i{ i~ isi 3 tl+i I,I iI'~~i'Ii+i its i P 9 Y Nitrate las Nl lppml ~ ~. ni~~i 2.8 27-2.9 3.8 37 39 Iii)~ ii Il yli + '10£ i ~ ~{i ii+'i(dlii 6l!I 9~{+j IiI I+IL i+;+i;i qunoff from fertilizer use; Leaching from sewage; ;tQ;~` ~~1`,~ ~iij~~;i~li (I~i~l+iiN !.i sl(iI(Liiill!I(I~I(i';IIIjjll l j~ilj~I»1~Ii+~~Ii~i+~Erosion ofnaturaldePOSits Perchlorate lppbl ~E (~l s~ ND ND. ND ND Ilij!(1i~llly li131~R. i ~{}hlir ;~ pl Npi~lilil lilllii! ii+l jil Industrial waste discharge hsii s,!i IEs / t } Ilill a i~,il iii is s (ii lis I il~ii~~ III 113 uili 111! j 1'ti Radionuclides IE+°1~~~~~ ~v ~~ (ih'pi if ! (++ ( I (114i 4.I (IIII j~llli rpi~+ii i ~53~3 ~(s~l ~+~ E~ T: (jiljl~~ii p ' +1( F; (11 ~i (lit IJ161~(II~ ~ i~ i 1 i ~~ Alpha emitterslpCi/II liryi ~{,EE s~E IQ € '2.4 ND 4.0 5.2 52 Iilli52ii I h5 ~ 'E I f3 Ii ; Erosion of naturalde osits ~i 131 S{ E1, ~ tS E~'3{p III IiI+ i{ j ~~ 7+Yry ~~Iit~~i IIIM ~il+ r Ili ji Il i+3Ei ~L P Beta/photon emitters lPCi/II s3s l1'{9'e~~ll l{EE~~1 ~s~#i! N/A N/A N/A N/A iil'i~l~i$I111 N4LB7 dsi ~~I{ii: ill (i(IVD (~i "~31 si .++ Deca of naturaland man-made de osits Combined RadmmlpCi/I) v1 °i ~i1 E, 1~~'p~E~R i ( Ixi dlu 9 ¢ r ns j, ~~ l~l ii: 3. Y P s1 E 3 1 ~ Q ND NO ND ND Ipin +1 i 1 i II II ~ ii. i I ~E~~I '~11(~3~13~~i I~~j131 Ij~Ifi"~Iilillil l{ iiNli~•~llii jA I'IE(~(~~r~i~`Ii~.IIi I~t 1311{/ Erosion of natural deposits UranmmlpCi/ll 1 i ~ IH33°ii iii'3 4,1 40-4.1 0.67 087 ili3~ IjIillii it lF~~ i i+a t: li ~r l~li, is+i ill !!{' Erosion ofnaturaltle osits 3 ,.~ 1~3~~ p~ 3• ~ I II I~y ~ ~ ~ (((ICICII~ ' ( P ~~~3~ 1 s~Pv,~~1~~ 3~SiIi3=~,S~1,~~0 EI i3i5(41iil IIII {Ili its ~~n li ~f i , Z~,..,°Q °! tl~~ii~~~(141~I3i~1li~j~( ij KEY TO A98REVId1T10NS Primary Drinking Water Standards = MCLS for contaminants that affect health along with their moni[orinq and reporting requirements, and water treatment requirements. PHG =Public Health Goel, or the level of a contaminant in drinking water below which there is no known or expected risk to healilt. PHGs are se[ by the California Environmental Protection Agency. MCLG =Maximum Contaminant Level Goai, or the level of a contaminant in drinking water below which there is no known or expected risk ro heykh. MCLGs are set by the U.S, Environmental Protection Agency. MCL =Maximum Contaminant Level; m the highest level of a contaminant that is allowed in drinking water. Primary MCLS are set as close to the PHGs for MCLGsI as is economically and technologically feasible. MRGLG =Maximum Residual Disinfectant Level Goal, or the level of no expected risk to health. MRGL=Maximum Residual Disinfectant Level, orthe level ofa disinfectant added for lal=For 2008, the Arcadia well watertreatmentplanttreatetla blend of 45Yo well water water treatment tltal may no[ he exceeded in the consumer's tap. and 55% imported surface water N/A=NOt Applicable IbI=SM Wellki is pumped into atransmissian line, is blended with Imported Surface AL=Action Leval,orthe concentration ofa contaminant which, when exceeded, Water and enters the system at 19th St &Itlaho Ave. triggers treatmem or other requirements which a water system must follow. Ic1= We are novequired [o test for every parameter each year. If indicated, data is NS = No Standard from a previous year. NG =Monitored far but Not Detected Itll =Two consecutive Total Coliform-positive samples, one of which contains Fecal NTU=Nephelometric Turbidity Units-used [o measure cloudiness of drinking water. Coliform/E. Coll constiNtes an acute MCL violation. No violations occurred for 2008. ppb =parts per billion, or micrograms per liter (pg/II lei =The MCL has been replaced with a treatment technique requiring agencies to ppm =parts per million, or milligrams par liter mg/II optimize corrosion control. Results given are from first draw, at-the-tap monitoring pCi/1=picocuries per liter performed every three years. * = secondary standard For additional water quality questions, rontact M. Cardenas,Princdpal Water Chemist at 310-826-6712 CITY OF SANTA MG7NICA WATER DIVISf6N ~a~~m~ry ~~ F~rirro~rr~r C51rir~l~.it~~ iiVafier £3.`a~llity Fie~ca~~s fot~ ~C9 Parameter C arit Maximum Turbidity NTU{ M_igrohioloaical Total Coliform Bacteria (% positive samples/month{ Fecal Coliform/E. Coll Ornnn'c Che ti r.?I Methyl tart-Butyl Ether (MTBEI IPpbl Trichlaraeihylene Ipphl Bisinfecfion Byproducts & Residuals Total Trihalomethanes Ippbl Halaacetic Acids (ppb{ Total Chlorine/Chloramines Ippml Bromate Ippb) Inornanic Chemicals Aluminum Ippml Arsenic Ippbl Barium Ippml Copper let lppml Fluoride After Treatment Ippm1 Lead let (Ppbl Nitrate lay N{ (ppml Perchlorate IpVb) Radionuclides Alpha emitters IpCi/II Beta/photon emitters IpCi/I{ Combined Radium IPDI/II Uranium IpCi/q SM WELLfltlh) ' N/A N/A. 4 N/A '. N/A ~~~~~~~3~~~~iii~i~('~~l~h~ili'r~ii~~~iY~~ °:iI13iIIIIIIilliiliili~ilii~~I~~~IIIII~~~~t~9i~Ellllii~~i~~~i~t t '..ND ND'.' , ND :. NO IV/H IV/H.. IV/H IV/H :. 006 0.06 -'07 001 001 r tl7 15<1.8 09 0.9 '.009 O.OG•0.11 005 05 X32 28:-.4.0 38 I 37-4.0 'ND ND' ND ND 4fi 45-4.6 ND ND :' f:. N/A N/A'.. NIA N/A ,. '. ND ND ND ND 4 5 4 5 0 88 0 88 :' MAJOR SOURCES IN DRINKING WATER Soil runoff Naturally presmriin [he environmmtt Human and animal fecal waste leaking underground storage tmdcs Discharge from metal degreasing sites By-product of drinking water chlorination By-product of drinking water chlorination Drinking water disinfectant added for treatment By-product of drinking water ozonation Erasion of natural deposits; used in water treatment process Erosion of natural deposits Discharge from oil and metal industries; Erosion of natural deposits Corrosion of household plumbing systems Water additive for dental health Corrosion of household plumbing systems Runoff from fertilizer use; Leaching from sewage; Erosion of natural deposits Industrial waste discharge Erosion of natural deposits Decay of natural and man-made deposits Erosion of natural deposits Erosion of Itatural deposits KEY TQ ABB REVIATlQftIffi Primary Drinking Wntnr Standards =MCLS for conlaminanis that affect health along with their monimring and reporting raquiromxnts, and water treatment requirements. PH6 = Public Heafih Goal pr the level of a contaminant in drlnking water below which [here is no known or expected risk to health. PHGs are se[ by the Galifornio Environmental Protection Agency. MCLG =Maxbnum Contnminant Laval Goal, or dm level of a comeminant In drlnking water below which (hero is no known or expected risk to health. MCLGS are set by the U.S. Environmental Protection Agency. MGL=Maximum Contaminant Level, nr iha highest lovol of a contaminant that is allowed in drinking water. Primary MCLS are sot as close to the PH6s for MCLOSI ns is economically and technologically feasible. MROLG =Maximum Residual Disinfectant Laval Goal, or the level of a drinking water disinfectant below which there is noknown or expected rik to health. They do nut reflect the benefits of the use of disinfectants m control microbials. MROL=Maximum Residual Disinfectant Levet, orthe highest level ofatlisinfectam lal=. For 21199, the Arcadia well watertreatment plant treatetla blend o145%well allowed in drinking water. There is convim:inq evidence that addition ofa water and 55%imported surface water. dlslntectent is nocessary for control of lnicroblal oontaminants. pd= SM WOIlY1 is pumped intpotransmieslon lion, Is bleudetl with Imported SUrtoce N/A=Not ApplicaGle Water and enters the system at 19th SL&Itlaho Ave. AL=Action Level, nr the concentration ota contaminan[which, when exceeded, Ic1= We are nut requiredto test for every parantetar each year.lf intliratetl, data is triggere tremment or other mVUiremenis whirhawater sysfam must follow. fromapmvinus year. NS=NO Standard Id1= Two consatuHVe Total COliform-positive samples, one of whlgh oontolns fecal NO =Monitored for bm Not Detected Coliform/E. Coll constitutes an acute MCL violation. No violations occurred far NTU=Nephelometric Turbidity Units-used hl measure cloudiness pf drinking water. 3ag9. pph=peas per billion, or micmgmms per liter lp9lll Iel - The MCl has been replaced with atreannent technique requiring agencies ppm =pmts per million, or mllllgmlre par Ilter Imy/ll m optimize cormeion control. Results given are from first tlmw, et-the-tap poi/1=picocuries per liter monimring performed every thrna years. "=secondary standard Far addiiianai water quality quastians, contest M. Cardenas, Assistant Manager for Water Produetidn and Treatment at 37G-RZG-G7'12 EXHIBIT E COST ESTIMATES FOR TREATMENT TECHNOLOGIES (INCLUDES ANNUALIZED CAPITAL AND 08M COSTS) Estimated 2007* .Treatment unit Cost No Source of Information Technology ($/1,000 gallons treated Granular Reference: Malcolm Pirnie estimate for California Urban Water Agencies, large surface 1 Activated Carbon water treatment plants treating water from the State Water Project to meet Stage 2 D/D and bromate regulation, 1998 0.46 - 0.8784 2 Granular Reference: Carollo Engineers, estimate for VOC treatment (PCE), 95 % removal of PC , 0.21 Activated Carbon Oct. 1994,1900 gpm design rapacity Granular Reference: Carollo Engineers, est. for a large No. Calif. suit. water treatment plant (90 3 Activated Carbon mgd capacity) treating water from the State Water Project, to reduce THM precursors, ENR ti t i d = 6262 S F i 1992 1.017 construc on cos n ex ( an ranc sco area) - 4 Granular Reference:. CH2M Hill study on San Gabriel Basin, for 135 mgd central treatment facili 0.394 - 0.5783 Activated Carbon for VOC and SOC removal by GAC, 1990 5 Granular Reference: Southern California Water Co. -actual data for "rented" GAC to remove 1.$23 Activated Carbon VOCs (1,1-DCE), 1.5 mgd capacity facility, 7998 6 Granular Reference: Southern California Water Co. -actual data for permanent GAC to remove 1.178 Activated Carbon VOCs (TCE), 2.16 mgd plant capacity, 1998 Reference: Malcolm Pirnie estimate for California Urban Water Agencies, large surface 7 RBVerSe OSMOSIS water treatment plants treating water from the State Water Project to meet Stage 2 D/D 1.367 -2.616 and bromate regulation, 1998 Reference: Boyle Engineering; RO cost to reduce 1000 ppm TDS in brackish $ Reverse Osmosis groundwater in So. Calif., 1.0 mgd plant operated at 40 % of design flow, high brine line 3.224 cost, May 1991 Reference: Boyle Engineering, RO cost to reduce 1000 ppm TDS in brackish 9 Reverse 0$mosis groundwater in So. Calif., 1.0 mgd plant operated at 100 % of design flow, high brine lin 1.9$4 cost, May 1991 Reference: Boyle Engineering, RO cost to reduce 1000 ppm TDS in brackish 1 U RBVerSe Osmosis groundwater in So. Calif., 10.0 mgd plant operated at 40% of design flow, high brine lin 2.15 cost, May 1991 Reference: Boyle Engineering, RO cost to reduce 1000 ppm TDS in brackish 11 RBVerSe OSrt10SIS groundwater in So. Calif., 10.0 mgd plant operated at 100 % of design flow, high brine li e 1.66 cost, May 1991 12 Reverse OSMOSIS Reference: Arsenic Removal Study, City of Scottsdale, AZ - CH2M Hill, fora 1.0 mgd 5.394 plant operated at 40 % of design capacity, Oci. 1991 13 Reverse Osmosis Reference: Arsenic Removal Study, City of Scottsdale, AZ - CH2M Hill, fora 1.0 mgd 3.19 plant operated at 100 % of design rapacity, Oct. 1991 14 RBVer58 Osmosis Reference: Arsenic Removal Study, City of Scottsdale, AZ - CH2M Hill, fora 10.0 mgd 2 39 plant operated a[ 40% of design capacity, Oct. 1991 15 Reverse Osmosis Reference: Arsenic Removal Study, City of Scottsdale, AZ - CH2M Hill, fora 10.0 mgd 1.48 plant operated at 100% of design capacity, Oct. 1991 16 RBVefSe Osmosis Reference: CH2M Hill study on San Gabriel Basin, for 135 mgd central treatment facili 1.485 - 2.616 with RO to remove nitrate, 1990 17 Packed Tower Reference: Analysis of Costs for Radon Removal... (AW WARF publication), x.66 Aeration Kennedy/Jenks, fora 1.4 mgd facility operating at 40 % of design capacity, Oct. 1991 18 Packed Tower Reference: Analysis of Costs for Radon Removal... (AW WARF publication), 0.46 Aeration Kennedy/Jenks, fora 14.0 mgd facility operating at 40 % of design capacity, Oct. 1991 Packed Tower Reference: Carollo Engineers, estimate for VOC treatment (PCE) by packed tower 19 Aeration aeration, without off-gas treatment, O&M costs based on operation during 329 days/yea 0.22 at 10 % downtime, 16 hr/day air stripping operation, 1900 gpm design capacity, Oct. 19 Page 1 of 2 COST ESTIMATES FOR TREATMENT TECHNOLOGIES (INCLUDES ANNUALIZED CAPITAL AND 08M COSTS) Estimated 2007* Treatment unit Cost No. Source of Information Technology ~$/1,00o gallons treated Packed Tower Reference: Caroilo Engineers, for PCE treatment by Ecolo-Flo Enviro-Tower air strippi 20 ~ Aeration without off-gas treatment, O&M costs based on operation during 329 days/year at 10 % 0.24 downtime, 16 hr/day air stripping operation, 1900 gpm design capacity, Oct. 1994 21 Packed Tower Reference: CH2M Hill study on San Gabriel Basin, for 135 mgd central treatment facilit 0.3680 - 0.6046 Aeration acked tower aeration for VOC and radon removal, 1990 p Advanced Reference: Carolio Engineers, estimate for VOC treatment (PCE) by UV Light, Ozone, 22 Oxidation Hydrogen Peroxide, O&M costs based on operation during 329 dayslyear at 10 % 0.45 Processes downtime, 24 hr/day AOP operation, 1900 gpm capacity, Oct. 1994 Reference: Malcolm Pirnie estimate for CUWA, large surface water treatment plants 23 Ozonation using ozone to treat water from the State Water Project to meet Stage 2 D/DBP and 0.1051 - 0.2080 bromate regulation,Cryptosporidium inactivation requirements,1998 24 Ion Exchange Reference: CH2M Hill study on San Gabriel Basin, for 135 mgd central treatment facilit 0.4995 - 0.6441 ion exchange to remove nitrate, 1990 Note: "Costs were adjusted from date of original estimates to present, where appropriate, using Engineering News Record (ENR) construction indices for Los Angeles and San Francisco. Page 2 of 2 EXHIBIT F ACRONYMS ACWA -Association of California Water Agencies AL -Action Level BAT -Best Available Technology Cal/EPA -California Environmental Protection Agency CCR -California Code of Regulations CDPH -California Department of Public Health DBP -Disinfection Byproduct DLR -Detection Level for purposes of Reporting GAC -Granular Activated Carbon MCL -Maximum Contaminant Level MCLG -Maximum Contaminant Level Goal mg/I -milligrams per liter MWD -Metropolitan Water District ND -Not Detected NL -Notification Level OEHHA -Office of Environmental Health Hazard Assessment pCi/I - picoCuries per liter PHG -Public Health Goal PTA -Packed Tower Aeration RAA -Running Annual Average RO -Reverse Osmosis TCE -Trichloroethylene TTHMs -Total Trihalomethanes USEPA-United States Environmental Protection Agency VOC -Volatile Organic Compound Attachment B Summary of City of Santa Monica Report on Water Quality Relative to Public Health Goals Each year, the City of Santa Monica sends out its Annual Water Quality Report which includes details about the water that Santa Monica residents and businesses use every day. Along with information regarding important current water issues, the annual report includes information required by the Federal and State Governments to illustrate how the quality of the water at the consumer's tap compares against established water quality standards. These water quality standards are established by Federal and state regulations as MCL's (Maximum Contaminant Levels). Consistently, Santa Monica's water is shown to be in full compliance with all regulatory water quality standards. Every three years, a special report is required to be prepared by all water agencies in California to describe how the water quality compares against a different set of standards, known as Public Health Goals (PHG's). PHG's are levels of contaminants much lower than MCL's. Because they are goals, and not legally enforceable standards like MCL's, certain elements in the water may exceed the established public health goal while still remaining below the allowable MCL. For the period from 2007 to 2009 in Santa Monica, public health goals were exceeded for six unique elements. Although these elements exceed Public Health Goals, Santa Monica's drinking. water- meets all State and Federal drinking water standards. Details about Public Health Goals, how they were developed, what they mean, and the current state of the City's water quality are included in the 2010 Citv of Santa Monica Report on Water Quality Relative to Public Health Goals. The report will be received and filed at a public hearing by the Santa Monica City Council on Tuesday, October 26. Public comments can also be heard at this time. This report is available for public review at the City Clerk's office in City Hall, the Main Library, the Water Resources Division office, and online at the Water Resources Division at http://www.smgov.net/departments/publicworks/water.aspx .